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OCR for page 83
Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot
Appendix B
SCWO Reliability and Maintenance (RAM) Log for 500-Hour HD Hydrolysate Run
The data in Table B-1 were collected during the General Atomics engineering design study testing on the use of supercritical water oxidation (SCWO) technology as a secondary treatment step in the General Atomics Total Solution (GATS) for disposal of the mustard-agent-containing munitions stored at the Pueblo Chemical Depot.
REFERENCE
General Atomics. 2001. Assembled Chemical Weapons Assessment (ACWA), Engineering Design Studies, Draft Test Report, February 10. San Diego, Calif: General Atomics, Inc.
OCR for page 84
Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot
TABLE B-1 SCWO Reliability and Maintenance (RAM) Log for 500-Hour HD Hydrolysate Run
ID
Date
Time
Description of Item
GA Log Book No.
Page No.
Shutdown Caused?
Fix Time (hr)
Problem Type
System/ Component Involved
1
1/4/01
0:56
Nozzle plug
11574
56
Y
<1
Operational
Feed nozzle
2
1/5/01
12:07
Liquid letdown valve (Badger) repair
11574
58
N
2
Mechanical
Liquid letdown
3
1/5/01
12:07
Liquid letdown valve cannot hold level
11574
58
N
2
Mechanical
Liquid letdown
4
1/5/01
14:30
Gas/liquid separator gasket fails
11574
58
N
4
Mechanical
Gas/liquid separator
5
1/5/01
17:00
Low-pressure feed pump housing cracked
NA
NA
N
2
Error
Feed recirculation pump
6
1/5/01
17:40
Feed pump erratic
11574
59
N
<1
Operational
Feed pump
7
1/6/01
4:00
Gas analyzers erratic
11574
62
N
<1
Operational
Gas analysis train
8
1/6/01
8:10
TE-600 faulty reading
11574
62
N
<1
Operational
Reactor
9
1/6/01
8:20
Heat tracing on hot line
11574
62
N
<1
Error
Reactor
10
1/6/01
8:20
PT-463 faulty reading
11574
62
N
<1
Electrical
Air line
11
1/6/01
9:15
Letdown system solids accumulation
11574
63
N
1
Operational
GLS, hydroclone
12
1/6/01
9:18
Fuel pump packing repair
11574
63
N
2
Mechanical
Fuel pump
13
1/6/01
10:18
Gas analyzers not consistent with computer
11574
64
N
<1
Electrical
Gas analysis train
14
1/6/01
10:55
Feed pump erratic
11574
64
N
<1
Operational
Feed pump
15
1/6/01
16:38
Liquid letdown valve (Badger) repair
11574
66
N
2
Mechanical
Liquid letdown
16
1/6/01
18:45
Fuel line plug
11574
66
Y
2
Operational
Fuel tank
17
1/6/01
22:00
Fuel pump packing repair
NA
NA
N
2
Mechanical
Fuel pump
18
1/6/01
23:30
Gas sample line plug
11575
2
N
<1
Operational
Gas analysis train
19
1/7/01
14:20
Reactor plug
11574
71
Y
3
Operational
Reactor
20
1/7/01
19:23
Air flow control poor
11574
71
N
<1
Operational
Air line
21
1/8/01
12:49
Reactor bypassing
11574
75
Y
4
Operational
Reactor
22
1/8/01
15:33
Thermowell replacement
11574
76
N
<1
Corrosion
Reactor
23
1/8/01
18:00
Letdown system solids accumulation
NA
NA
N
1
Operational
GLS, hydroclone
24
1/8/01
20:33
Feed cross leak
11574
76
N
2
Error
Reactor
25
1/8/01
21:57
Reactor dump valve leak
11574
76
N
<1
Mechanical
Reactor
26
1/8/01
22:49
Nozzle plug
11574
76
N
4
Operational
Feed nozzle
27
1/8/01
22:57
Water pump ruptured diaphragm
11574
76
N
2
Mechanical
Water pump
28
1/9/01
2:32
Reactor surface TEs (thermocouples) faulty readings
11574
77
N
1
Electrical
Reactor
29
1/9/01
3:27
Badgers not working in auto mode
11574
77
N
<1
Computer
Computer
30
1/9/01
4:45
Computer type mismatch
11574
77
N
<1
Computer
Computer
31
1/9/01
6:47
Feed pump erratic
11574
77
N
1
Operational
Feed pump
32
1/9/01
6:50
Computer type mismatch
11574
77
Y
<1
Computer
Computer
33
1/9/01
9:50
Low-pressure feed pump seized
11574
78
N
1
Operational
Feed recirculation pump
34
1/10/01
10:00
Gas sample line plug
11574
85
N
<1
Operational
Gas analysis train
35
1/11/01
0:00
pH electrode fouled
NA
NA
N
<1
Operational
Liquid analysis train
36
1/11/01
16:36
Gas sample line plug
11574
94
N
<1
Operational
Gas analysis train
37
1/11/01
5:30
Clean P-350B check valves
11574
98
N
1
Operational
Feed pump
38
1/12/01
7:00
Badgers not working in auto mode
11574
99
N
<1
Computer
Computer
39
1/12/01
7:00
Bypassing behind Ti liner
11574
99
N
<1
Mechanical
Reactor
40
1/12/01
7:00
Potential computer problems
11574
99
N
<1
Computer
Computer
41
1/12/01
7:00
Thermowell replacement
11574
99
N
<1
Corrosion
Reactor
42
1/12/01
10:32
Liner thermocouple malfunction
11574
99
N
1
Mechanical
Reactor
43
1/12/01
15:07
pH meter apparently broken
11574
100
N
2
Mechanical
pH meter
44
1/12/01
15:35
Fuel tank runs dry
11574
100
Y
3
Error
Fuel system
45
1/12/01
19:00
PCV-437A not holding pressure
NA
NA
N
<1
Operational
Fuel system
46
1/12/01
19:39
Ruptured cooling water hose
11574
101
Y
<1
Operational
Cooldown HX
47
1/12/01
22:00
Added scaling chemicals to cooling water
NA
NA
N
<1
Operational
Cooling water system
48
1/13/01
14:14
Gas sample line plug
11575
2
N
<1
Operational
Gas analysis train
49
1/13/01
14:49
Compressor filters need replacing
NA
2
N
1
Operational
HP air compressors
50
1/13/01
21:58
PCV-357B not holding pressure
11575
4
N
<1
Operational
Feed system
51
1/13/01
21:58
Clean P-350B check valves
11575
4
N
1
Operational
Feed pump
52
1/13/01
21:58
P-420B B head leaking
11575
4
N
<1
Operational
Fuel pump
53
1/14/01
18:30
Air flow fluctuations
11575
10
N
<1
Operational
HP air compressors
54
1/14/01
23:50
Discharge and suction check valves cleaned
NA
NA
N
<1
Operational
Feed system
55
1/15/01
4:00
Added scaling chemicals to cooling water
NA
NA
N
<1
Operational
Cooling water system
OCR for page 85
Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot
Component ID
Maintenance/ Fix Type
Root Cause of Problem
Resolution to Problem
NA
Operational modification
Feed precipitation
Leave preheaters on at low setting
FCV-654A
Change-out
Faulty installation, stem bent
Change-out valve, rebuild correctly
FCV-654B
Change-out trim
Solids in valve
Better solids separation prior to valve
GLS-630
Replace gasket
Temporary gasket in use
Procure proper gasket
P-300B
Replace
Pump overpressured during cleanout
Replace pump, exercise care when blowing out lines
P-350B
Clean (flush)
Solids in pump
Periodic cleaning/flushing, including inlet strainer
GS-680
Drain
Water carryover
Modify post-V-680 trap
TE-600
Reposition
Thermocouple out of position
Replace and secure thermocouple
NA
Reposition
Incorrect installation
Reposition heat tracing
PT-463
Replace
TBD
TBD
GLS-630, SS-640
Clean (flush)
Titanium corrosion
Periodic flushing
P-420B
Repair
Normal wear
Normal maintenance
GS-680
Check connections
Connections incorrect
Correct connections
P-350B
Clean (flush)
Solids in pump
Periodic cleaning/flushing, including inlet strainer
FCV-654A
Adjustment
Improper adjustment
Adjust
TK-400B
Clean
Dirty fuel
Screen fuel when adding
P-420A
Repair
Normal wear
Normal maintenance
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
R-550
Clean (flush)
Failure to rinse after prior run
Rinse reactor before restarting if feed processed for >0.5 hr
FCV-461
Adjustment
Improper adjustment of control pressure
Reset control pressure
R-550
Clean (flush)
Nonoptimal top insert and gasket
Install new top insert and gasket
R-550
Replace
Corrosion
Replace
GLS-630, SS-640
Clean (flush)
Titanium corrosion
Periodic flushing
R-550
Replace
Improper installation
Review assembly procedures with pipe fitters
FV-550
Replace
Normal wear
Rebuild
NA
Clean (flush)
Metal burr from feed cross (see no. 15)
Assemble fittings without galling
P-120B
Repair
Nozzle plug
Assemble fittings without galling
TE-554
Replace
Wet leads
Waterproof thermocouple connections
NA
Programming
Software problem
Edit program
NA
Programming
Software problem
Switch computers
P-350B
Clean (flush)
Solids in pump
Periodic cleaning/flushing, including inlet strainer
NA
Programming
Software problem
Edit program
P-300B
Clean (flush)
Solids precipitation in pump and lines
Clean
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
AE-670
Clean (flush)
Solids buildup in probe housing
Periodic cleaning/flushing
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
P-350B
Clean
Preventative maintenance
Clean
NA
Programming
Software problem
Edit program
R-550
Redesign
Mismatched components
New top insert and gasket
NA
Reboot
Power fluctuations
Reboot
R-550
Replace
Corrosion
Replace
TE-572x, 574x
Replace
Normal wear
Replace
AT-670
Replace
Unknown
Not resolved at this time
TK-400B
Refill
Hourly rounds neglected
Carry out hourly rounds
PCV-437A
Repair
Stem and seat worn
Rebuild
HX-610
Repair
Hose overheats, presumably blockage
Rework hoses
Cooling water
Added Nalco chemicals
Potential scaling in cooling water
Treat cooling water
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
C-450
Change filter
Preventative maintenance
Changed desiccant air dryer filters on all compressors
PCV-357
Rebuild
Stem and seat worn
Rebuild
P-350B
Clean
Preventative maintenance
Clean
P-420B
Replace packing
B head leaking (packing)
Changed packing on B head
C-450
Adjustment
Insufficient compressor pressure
Set start pressure lower
P-350B
Clean
Preventative maintenance
Disassemble and clean
Cooling water
Added Nalco chemicals
Potential scaling in cooling water
Treat cooling water
OCR for page 86
Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot
ID
Date
Time
Description of Item
GA Log Book No.
Page No.
Shutdown Caused?
Fix Time (hr)
Problem Type
System/ Component Involved
56
1/15/01
16:24
Gas sample line plug
11575
17
N
<1
Operational
Gas analysis train
57
1/16/01
0:35
Scaling in the DPT lines
11575
20
N
<1
Operational
Reactor DPT
58
1/16/01
0:35
Hose replacement for cooling water to CDHX
11575
20
N
1
Operational
Cooling water system
59
1/16/01
0:35
Bad trim for FCV-654B
11575
20
N
<1
Operational
Liquid letdown
60
1/16/01
0:35
PCV-357B not holding pressure
11575
20
N
<1
Operational
Feed system
61
1/16/01
0:35
Discharge and suction check valves cleaned
11575
20
N
<1
Operational
Feed system
62
1/16/01
0:35
Thermowell replacement
11575
20
N
<1
Corrosion
Reactor
63
1/16/01
0:35
TE-571 broken on disassembly
11575
20
N
<1
Mechanical
Reactor
64
1/16/01
11:00
PCV-357A not holding pressure
NA
NA
N
<1
Operational
Feed system
65
1/16/01
17:27
Gas sample line plug
11575
26
N
<1
Operational
Gas analysis train
66
1/16/01
3:00
Discharge and suction check valves cleaned
11575
28
N
<1
Operational
Feed system
67
1/17/01
3:00
Added scaling chemicals to cooling water
11575
28
N
<1
Operational
Cooling water system
68
1/17/01
12:17
Gas sample line plug
11575
31
N
<1
Operational
Gas analysis train
69
1/17/01
17:00
HP air compressor C malfunction
11575
32
N
2
Mechanical
HP air compressors
70
1/18/01
2:45
PCV-460 not controlling properly
11575
35
N
<1
Operational
HP air line to reactor
71
1/18/01
9:35
Gas sample line plug
11575
37
N
<1
Operational
Gas analysis train
72
1/19/01
5:00
TE-571 broken on disassembly
11575
42
N
<1
Mechanical
Reactor
73
1/19/01
5:00
Thermowell replacement
11575
42
N
<1
Corrosion
Reactor
74
1/20/01
12:15
pH meter apparently broken
11575
48
N
2
Mechanical
pH meter
75
1/20/01
14:00
TE-641 malfunction
11575
48
N
<1
Mechanical
Letdown system
76
1/20/01
19:27
Gas sample line plug
11575
49
N
<1
Operational
Gas analysis train
77
1/20/01
20:10
Line from PT-551 to reactor head leaking
11575
50
Y
2
Mechanical
Reactor plumbing
78
1/20/01
22:12
Shutoff valve on gas letdown leaking
11575
50
N
2
Mechanical
Gas letdown
79
1/20/01
22:12
Reactor dump valve leaking
11575
50
N
2
Mechanical
Reactor
80
1/20/01
22:12
BPR on gas letdown not holding pressure
11575
50
N
2
Mechanical
Gas letdown
Source: General Atomics, 2001.
OCR for page 87
Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot
Component ID
Maintenance/ Fix Type
Root Cause of Problem
Resolution to Problem
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
DPT-550
Clean (flush)
Salts build up in DPT lines
Flush lines
HX-610
Replace
Possible coolant overheating
Replace with high-temperature hose
FCV-654B
Replace
Scored trim, trim too large
Replace with M trim
PCV-357B
Clean
Dirty stem and seat
Disassemble and clean
P-350B
Clean
Preventative maintenance
Disassemble and clean
R-550
Replace
Corrosion
Replace
TE-571
Replace
Thermowell corrosion
Replace
PCV-357A
Clean
Dirty stem and seat
Disassemble and clean
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
P-350B
Clean
Preventative maintenance
Disassemble and clean
Cooling water
Added Nalco chemicals
Potential scaling in cooling water
Treat cooling water
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
C-450C
Repair
Check valve broken
Repair
PCV-460
Replace
Oil contamination/clogging frit
Disassemble and rebuild
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
TE-571
Replace
Thermowell corrosion
Replace
R-550
Replace
Corrosion
Replace
AT-670
Replace
Interference from power wiring
Rearrange wiring
TE-641
Replace
Unknown
Replace with surface thermocouple
V-680
System modification
Mist carryover with salt deposition
Modify post-V-680 trap
NA
Replace
Fatigue/wear/corrosion
Weld new fitting to modified AE drilled through plug
FV-640B
Replace
Contamination in gas letdown
Replace
FV-550
Replace body
Overheating soft goods
Replace
PCV-646
Replace
Corrosion/erosion internals
Replace
Representative terms from entire chapter:
gas letdown