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Electricity from Renewable Resources: Status, Prospects, and Impediments (2009)
National Academy of Sciences (NAS)

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION 3 Renewable Electricity Generation Technologies A renewable electricity generation technology harnesses a naturally existing energy flux, such as wind, sun, heat, or tides, and converts that flux to electricity. Natural phenomena have varying time constants, cycles, and energy densities. To tap these sources of energy, renewable electricity generation technologies must be located where the natural energy flux occurs, unlike conventional fossil fuel and nuclear electricity generating facilities, which can be located at some distance from their fuel sources. Renewable technologies also follow a somewhat different paradigm than conventional energy sources in that renewable energy can be thought of as manufactured, with the largest proportion of costs, external energy, and material inputs occurring during the manufacturing process. Although conventional sources such as nuclear- and coal- powered electricity generation have a high proportion of capital-to-fuel costs, all renewable technologies, except for biomass-generated electricity (biopower), have no fuel costs. The trade-off is the ongoing and future cost of fossil fuel against the present fixed capital costs of renewable energy technologies. Scale economics likewise differs for renewables and conventional energy production. Larger coal-fired and nuclear-powered generating facilities exhibit lower average costs of generation than do smaller plants, realizing economies of scale based on the size of the facility. Renewable electricity achieves economies of scale at the equipment manufacturing stage rather than through construction of large facilities at the generating site. Large hydroelectric generating units are an exception and have on-site economies of scale, but not to the same extent as coal- and nuclear-powered electricity plants. With the exception of hydropower, renewable technologies are often disruptive and do not bring incremental changes to long-established electricity industry sectors. As described by Bowen and Christensen (1995), disruptive technologies present a package of performance attributes that, at least at the outset, are not valued by a majority of existing customers. Christensen (1997) observes: Disruptive technologies can result in worse product performance, at least in the near term. Disruptive technologies bring to market very different value propositions than had been available previously. Generally, disruptive technologies underperform established products in mainstream markets. But they have other features that a few fringe customers value. Disruptive technologies that may underperform today, relative to what users in the market demand, may be fully performance–competitive in that same market tomorrow (Christensen, 1997). 47

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION Traditional sources of electricity generation at least initially outperform non-hydropower renewables. The environmental attributes of renewables are the initial value proposition that have brought them into the electricity sector. However, with improvements in renewables technologies and increasing costs of generation from conventional sources (particularly as costs of greenhouse gas production are incorporated), renewables may offer the potential to match the performance of traditional generating sources. This chapter examines several technologies for generation of renewable electricity. It discusses the technology associated with each renewable resource, the state of that technology, and research and development needs until 2020, between 2020 and 2035, and those beyond 2035. WIND POWER Wind power uses a wind turbine and related components to convert the kinetic energy of moving air into electricity and other forms of energy. Wind power has been harnessed for centuries—from the time of the ancient Greeks to the present. The modern era of wind-driven electrical generation began with the oil shocks of the 1970s and accelerated in the 1980s with the passage of the Public Utilities Regulatory Policies Act (PURPA). Both the development of wind technology and the installation of wind power plants have grown ever since. Status of Technology System Components A typical wind turbine consists of a number of components: rotor, controls, drive train (gearbox, generator, and power converter), tower, and balance of system.1 Each of these components has undergone significant development in the last 10 years, with improvements integrated into the latest turbine designs. In addition, improved understanding and better modeling capabilities have contributed to the rapid introduction of technical improvements. What were initially small clusters of 100 kW turbines in the early 1980s have grown to clusters of hundreds of machines, including machines of 1.5 MW or more. In general, wind speed increases with height, and the energy capture capability depends on the rotor diameter. Figure 3-1 shows the change in rotor diameter and rated capacity over time. In 2006 the most common installed machine had 275 ft (84 m) hub 1 In general, the balance of system (BOS) is the system between the technologies that convert the renewable flux (wind, or solar) into electricity and the electricity grid (for power production) or load (for direct use). The BOS might include the power-conditioning equipment that adjusts and converts the DC electricity to the proper form and magnitude required by an alternating-current (AC) load. For solar PV, the BOS consists of the structure for mounting the PV arrays and storage batteries. For wind turbines, it typically includes all the related electronics required to provide the connection to the grid. 48

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION heights and had a rotor diameter of 220 ft (67 m). Turbines as big as 5 MW have been installed in offshore locations; these have 505 ft (154 m) hub height and 420 ft (128 m) rotor diameter (IEEE, 2007a).2 As noted in Chapter 1, the U.S. wind energy industry installed almost 14,000 MW of capacity during 2007 and 2008. The U.S. wind power capacity is now more than 25 GW and spans 34 states; the world’s largest wind power plant, Horse Hollow Wind Energy center with a capacity of 750 MW, recently commissioned in Texas (SECO, 2008). U.S. wind farms will generate an estimated 52,000 GWh of electricity in 2008, about 1.2 percent of the U.S. electricity supply. As discussed in Chapter 1, the installed wind power generating capacity worldwide at the end of 2006 was 75,000 MW. Electrical Output Controls Besides the mechanical characteristics, the development of the turbine mechanical to electrical conversion characteristics have evolved from machines based primarily on fixed-speed induction generators (Type 1), to variable-speed machines with electronic control (Type 2), and then machines incorporating vastly different outputs and controls (Type 3). These Type 3 machines are able to control for low voltage ride-through (LVRT),3 voltage,4 output5 and ramp rate,6 and volt-ampere-reactive (VAR) support.7 While wind generators have increased in height and rotor diameter, the major changes in internal operating characteristics are not as apparent. Figure 3-2 depicts the evolution of the internal operating characteristics. Many perceptions of wind technology’s negative impact on the electrical system, such as the inability to remain connected to the electricity grid during voltage disturbances and the draw on the grid’s reactive power resources, stem from Type 1 machines. The evolution of control technologies has made wind generators and their electricity output easier to integrate into the utility system. With these new control technologies, wind power plants are better at mimicking traditional generating plants. This capability led to Federal Energy Regulatory Commission (FERC) Order 661-A, issued December 2005, which deals with machine design and system integration. It calls for wind facilities of 20 MW or larger to provide the ability to maintain operations, including LVRT, during disturbances on the electric grid; provide reactive power; and maintain continuous real-time communications and data exchange with the control area operator. These power integration capabilities have been incorporated into Type 3 machines. However, wind power generation takes place where and when the wind blows, and electricity must be used when it is generated. This intermittency has raised concerns 2 Background description and information on activities of the wind industry can be found on the American Wind Energy Association website at http://awea.org. 3 Under FERC order 661A, low voltage ride-through is the capability to continue to operate down to 15 percent of rated line voltage for 0.626 s and continuously at 90 percent of rated line voltage. This capability keeps the plant from shutting down as a result of short-term voltage fluctuation. 4 Voltage control ability provides control of wind turbine voltage output. 5 Power output ability allows the power produced to be reduced by feathering the blades. 6 Ramp rate management allows the power output to stay within the increase or decrease limits required by the system. 7 VAR support provides reactive power compensation to aid in electricity grid stability. 49

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION about integrating wind power into the existing power system and requires wind turbines to provide LVRT, voltage control, output and ramp rate controls, and VAR support. Integrating Type 3 machines into existing grids is not without its challenges. Circumstances such as wind fluctuations and overall grid stability are unique to each particular control area. Thus, even as technologies improve, it will be critical to carry out site-specific analyses of each control area, which will better aid grid operators in balancing the system within their control area. Integration into Utility System Operation A number of studies on the integration of wind power into a utility capacity and dispatch structure indicate that wind can be integrated at up to approximately 20 percent of the total electricity mix without requiring storage, although the exact level depends on the power system (Parson et al., 2006; ETSO, 2007; DOE, 2008).8 The specifics of these studies are discussed in this report in the chapters on economics (Chapter 4), deployment (Chapter 6), and scenarios (Chapter 7). As the studies point out, achieving such levels of renewables penetration will depend on upgrades to the grid (necessary regardless of the energy mix) and new transmission lines for more remote sources. Modern electricity grid systems are designed to handle loss of the largest power plant without disruption; to have ramp up and ramp down capabilities: and to increase or decrease generation as demand increases or decreases. However, each system has its own generating capacity structure, transmission capabilities, and ability to purchase power outside its own boundaries, making wind power integration somewhat unique for each utility. Small Wind Systems The vast majority of wind power is generated by large wind turbines feeding into the electricity grid, while small wind turbines generally provide electricity directly to customers. The United States is the leading world producer of small wind turbines. These residential turbines are erected and connected directly to the customer’s facility or to the electricity distribution system at the customer’s site. The manufacture and marketing of wind-powered electric systems sized for residential homes, farms, and small businesses have experienced major growth in the past decade. These small wind turbines (Figure 3-3), defined as 100 kW or less in capacity, have seen significant market growth, and the industry has set ambitious growth targets: growth at 18 to 20 percent through 2010. 8 A number of studies can be found on the Utility Wind Integration Group (UWIG) website at http://www.uwig.org. 50

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION Key Technology Opportunities Short Term: Present to 2020 The key technological issues for wind power focus on continuing to develop better turbine components and to improve the integration of wind power into the electricity system, including operations and maintenance, evaluation, and forecasting. Goals appear relatively straightforward: taller towers; larger rotors; power electronics; reducing the weight of equipment at the top and cables coming from top to bottom; and ongoing progress through the design and manufacturing learning curve (Thresher et al., 2007; DOE, 2008). Table 3-1 summarizes the incremental improvements under consideration. Although no big breakthroughs are anticipated, continuous improvement of existing components is anticipated, and many are already being actively developed. For example, there are advanced rotors that use new airfoil shapes specifically designed for wind turbines, instead of those based on the design of helicopter blades. These rotors are thicker at points of highest stress and reduce loads during turbulent winds by flying the blades using turbine control systems. Other improvements include the use of composite materials and advanced drive trains. In particular, gear boxes are a major area of concern for reliability. Approaches for improving of this component include direct drive generators; greater use of rare-earth permanent magnets in generator design; possibility of single-stage drives using low-speed generators; and distributed drive trains using the rotor to drive several parallel generators. Advanced towers are a major focus for innovation, given the current need for large cranes and transport of large tower and blade sections. Concepts under investigation include self-erecting towers, blade manufacturing on site, vibration damping, and tower drive train interactions. There is certain to be some development of offshore wind in the United States in the near term, but it is not expected that this will have a significant impact before 2020. Nonetheless, there is a near-term opportunity to learn from offshore projects in Europe and the United States, if offshore wind is going to have an impact in the medium term. Other near-term opportunities will lie in improving the integration of existing wind power plants into the transmission and distribution system, which includes using improved computational models for simulating and optimizing system integration (Ernst et al., 2007). Chapters 6 and 7 discuss the deployment and integration of wind-generated electricity. 51

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION TABLE 3-1 Areas of Potential Wind Power Technology Improvements Performance and Cost Increments (Best/Expected/Least Percentages) Annual Energy Turbine Capital Production Cost Technical Area Potential Advances • Advanced Tower +11/+11/+11 +8/+12/+20 Taller towers in difficult locations Concepts • New materials and/or processes • Advanced structures/foundations • Self-erecting, initial, or for service • Advanced (Enlarged) +35/+25/+10 −6/−3/+3 Advanced materials Rotors • Improved structural-aero design • Active Controls • Passive controls • Higher tip speed/lower acoustics • Reduced Energy Losses +7/+5/0 0/0/0 Reduced blade soiling losses and Improved • Damage-tolerate sensors Availability • Robust control systems • Prognostic maintenance • Drivetrains (Gearboxes +8/+4/0 −11/−6/+1 Fewer gear stages or direct-drive and Generators ad • Medium/low speed generators Power Electronics) • Distributed gearbox topologies • Permanent-magnet generators • Medium-voltage equipment • Advanced gear tooth profiles • New circuit topologies • New semiconductor devices • New materials (gallium arsende [GaAs], SiC) • Sustained, incremental design and 0/0/0 −27/−13/−3 Manufacturing and Learning Curvea process improvements • Large-scale manufacturing • Reduced design loads Totals +61/+45/+21 −36/−10/+21 a The learning curve results from the NREL report (Cohen and Schweizer et al., 2008) are adjusted from 3.0 doubling in the reference to the 4.6 doubling in the 20% Wind Scenario SOURCE: DOE (2008). Medium Term: 2020 to 2035 Mid-term wind technology development will have two thrusts: the movement toward offshore, and its implications for turbine design; and the development of efficient low-wind speed turbines. Development of offshore wind power plants has already begun in Europe (approximately 1200 MW of installed capacity), but progress has been slower in the United States. Nine projects are in various stages of development in state and federal waters. In addition to technical risks and higher costs, these projects have been slowed by social and regulatory challenges (DOE, 2008). 52

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION In the mid-term, offshore turbines will have a larger size and generating capacity than onshore turbines, but, due primarily to technical and cost concerns, development will likely lag behind onshore machines. Transmission siting issues with offshore wind power plants will be simplified because of fewer siting impediments. However, underwater cables must be carefully constructed, and there will likely be a move to develop microgrids with HVDC to integrate the offshore resources. Offshore wind technologies face several transition problems as they move from near-shore, land-based sites to offshore sites of various depths, and finally floating designs. Assessment tools for sensitive marine areas, wind loads, and system design are not now ready for offshore development. Offshore projects must be built to handle both wind and wave loads, and components must be able to endure marine moisture and extreme weather. Offshore wind projects have a higher balance of station cost (approximately 2/3 of total costs) than onshore projects, and thus will rely on cost reductions across the system in order to become more competitive. All of these developments pose both technological and organizational problems and will require continuous research and development in order to be feasible. It should be noted that challenges posed by the greater technical difficulties of offshore wind power development are being addressed by other countries. However, political, organizational, social, and economic obstacles may continue to inhibit investment in offshore wind power development, given the higher risk compared to onshore wind energy development (Williams and Zhang, 2008). In terms of onshore development, as the higher wind speed sites are used, wind power development will move to lower wind speed sites, which will require turbines that are relatively efficient at lower wind speeds, necessitating larger rotors with lighter, stronger materials, and increased tower height. Long Term: After 2035 At present, no revolutionary technology to extract energy from wind has been proposed, but several designs, e.g., vertical wind turbines or eggbeaters, are again under consideration. There have been conceptual proposals to access high-altitude winds using balloons or kites. Component improvements will continue, with additional emphasis on offshore turbine installation. Floating offshore platforms may gain interest, but first must come experience from anchored offshore wind facilities. Summary of Wind Power Potential Wind-power technologies are actively deployed today, and there are no technological barriers to continued deployment. Cost reductions will be possible as a result of wider deployment and incremental improvements in component. No other enhancing technologies are required for wind power to meet 20 percent and higher of U.S. electricity demand. 53

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION SOLAR PHOTOVOLTAIC POWER Solar power involves the conversion of the radiant energy from the sun into electricity by using photovoltaics (PV) or concentrating devices. When sunlight strikes the surface of the PV cell, some of the photons are absorbed and release electrons from the solar cell that are used to produce an electric current flow, i.e., electricity. A solar cell consists of two layers of materials, one that absorbs the light and the other that controls the direction of current flow through an external circuit (Figure 3-4). The absorbing materials can be silicon (Si), which is also used in integrated circuits and computer hardware; thin films of light-absorbing inorganic materials, such as CdTe or GaAs, that have absorption properties well matched to capture the solar spectrum; or a variety of organic (plastic) materials, nanostructures, or combinations. Status of Technology The PV industry has grown at a rate greater than 40 percent per year from 2000 through 2008. Much of this growth is the result of national and local programs targeted toward growing the PV industry and improving PV’s competitiveness in the marketplace. In 2007, PV modules supplying 3.4 GW were produced worldwide, and approximately 220 MW were installed in the United States.9 Table 3-2 provides a breakdown of PV module shipments by technology type. Over the past 30 years, the efficiency of PV technologies has steadily improved. Figure 3-5 presents the historical progress of the best reported solar cell efficiencies through 2008 (NREL, 2009). Commercial (or even the best prototype) modules achieve, on average only about 10 to 15 percent efficiency, which is 50 to 60 percent of the efficiency of the best research cells. Figure 3-5 includes several PV technologies: single- crystalline Si, thin films, multiple-junction cells, and emerging technologies, such as dye- sensitized nanocrystalline TiO2 cells, cells based on organic compounds, and plastic solar cells. Flat-Plate PV Technologies Photovoltaic technologies can be divided into two main types: flat plates and concentrators. Flat-plate technologies include crystalline silicon (from both ingot and ribbon- or sheet-growth techniques) and thin films of various semiconductor materials, usually deposited on a low-cost substrate, such as glass, plastic, or stainless steel, using some type of vapor deposition, or wet chemical process. Thin film cells typically are 1 to 20 μm in thickness and require one-tenth to one-hundredth of the expensive semiconductor material required by crystalline silicon (DOE, 2007f). Additionally, thin film deposition technology allows production of large-area solar cells, and though they exhibit lower efficiencies (upward of 10 percent) than crystalline silicon PV panels, their lower production costs can make them an attractive alternative. Even thinner layers are involved in some of the future generation technologies, such as organic polymers and nanomaterials (DOE, 2007j). 9 See http://www.solarbuzz.com/Marketbuzz2008-intro.htm. 54

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION TABLE 3-2 PV Cell and Module Shipments by Type, 2005-2007 Shipments (Peak Kilowatts) Percent of Total Type 2005 2006 2007 2005 2006 2007 Crystalline Silicon Single-Crystal 71,901 85,627 128,542 32 25 25 Cast and Ribbon 101,065 147,892 181,788 45 44 35 Subtotal 172,965 233,518 310,330 76 69 60 Thin-Film 53,826 101,766 202,519 24 30 39 a 1 1 Concentrator 125 1,984 4,835 b ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ Other U.S. Total 226,916 337,268 517,684 100 100 100 a Less than 0.5 percent. b Other includes categories not identified by reporting companies. NOTE: Totals may not equal sum of components due to independent rounding. ⎯, no data reported. SOURCE: EIA (2008), Table 3.5. Of the PV modules produced today, nearly 88 percent are based on crystalline silicon wafer technologies. Of this total, about 30 percent are based on conventional, single-crystal silicon grown by the Czochralski ingot process,10 60 percent are based on polycrystalline (also referred to as multicrystalline) ingots cast in a crucible, and 3 percent are from silicon ribbons/sheet produced by various processes. The typical efficiency of these crystalline PV cells is 12 to 18 percent, and further development is required to increase the efficiency and to lower the production cost (DOE, 2007e). Concentrator PV Technology The key elements of a concentrator PV system are low-cost concentrating (reflective or refractive) optics, low-cost mounting and tracking systems (to track the movement of the sun), and high-efficiency III-V11 or silicon solar cells (DOE, 2007g). The large-scale manufacturing capability for all components has already been demonstrated, including 27 percent efficient silicon cells and 28 percent efficient GaAs cells (DOE, 2007g; Surek, 2001). Concentrator systems using point-focus Fresnel lenses have been routinely fabricated. Module efficiencies of up to 20 percent have been demonstrated by commercially made 25 percent efficient silicon solar cells (DOE, 2005). Progress in multi-junction, III-V based solar cells for space applications has led to evaluating their terrestrial potential in concentrating applications (Bett et al., 1999; DOE, 2007g). An efficiency of 37.3 percent (at up to 600 times the sun’s normal intensity) has been achieved for a GaInP2/GaInAs/Ge triple-junction structure (King et al., 2004), and 10 A method of crystal growth commonly used to obtain single crystals of semiconductors. 11 III-V compounds (the III and V indicate the column location on the Periodic Table) are the basic materials for modern optoelectronic devices typically used in high-speed transistors (Bett et al., 1999). 55

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION NREL has recently announced an efficiency of almost 41 percent (at 380 suns intensity) (NREL Press Release, August 13, 2008). Concentrated photovoltaic (CPV) plants are composed of many aggregated photovoltaic modules, as are non-concentrator plants, but the required cell area is reduced by the concentration factor (DOE, 2005). The concentration ratio12 of one-axis CPV systems is commonly 10-50. High-concentration PV (HCPV) systems use two-axis trackers with concentration ratios of 200-500. Concentration makes the use of the most efficient and expensive PV cells more practical. Mature HCPV systems are projected to cost about 40 to 60 percent of standard PV systems and to provide 10 to 20 percent more energy with the same power rating. Projections put the installed costs of CPV with multi- junction PV cells now under development at about $2/W (DOE, 2007g). The present cost of single-junction systems from Amonix and Solar Systems Pty Ltd. is, for example, about $4/W. Potential Technology Development Future directions for thin film technologies include multi-junction thin films aimed at significantly higher conversion efficiencies, better transparent conducting oxide electrodes, thin polycrystalline silicon films, and organic inks. Concentrator systems use only direct, rather than diffuse or global, solar radiation; therefore, their areas of best application (e.g., in the southwestern United States) are more limited than those for flat plates. There is also ongoing research to improve the long-term reliability of concentrator systems and to develop standard tests for concentrator cells and systems. Thus, most of today’s remote and distributed markets for PV systems are not suitable for concentrator systems. By far the fastest-growing segment of the PV industry is that based on casting large, multicrystalline ingots in some crucible that is usually consumed in the process. Manufacturers routinely fabricate large multicrystalline silicon solar cells with efficiencies in the 13 to 15 percent range; small-area research cells are 20 percent efficient. Silicon ribbon or sheet technologies avoid the costs and material losses associated with slicing ingots. The present commercial approaches in the field are the edge-defined, film-fed growth of silicon ribbons and the string ribbon process. Full-scale production of silicon modules based on micron-sized silicon spheres was recently announced. In this process, submillimeter-size silicon spheres are bonded between two thin aluminum sheets, processed into solar cells, and packaged into flexible, lightweight modules. Another approach uses a micromachining technique to form deep narrow grooves perpendicular to the surface of a 1- to 2-mm thick single-crystal silicon wafer. This technique results in large numbers of thin (50 μm), long (100 mm), and narrow (nearly the original wafer thickness) silicon strips that are processed into solar cells just prior to separation from the wafer. In another technique, a carbon foil is pulled through a silicon melt, resulting in the growth of two thin silicon layers on either side of the foil. After the edges are scribed and the sheet is cut into wafers, the carbon foil is burned off, resulting in two silicon wafers (150 μm thick) for processing into solar cells. 12 Defined as the average solar flux through the receiver aperture divided by the ambient direct normal solar insolation. 56

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION Thin-film technologies have the potential for substantial cost advantages over wafer-based crystalline silicon, because of factors such as lesser material use due to direct band gaps, fewer processing steps, and simpler manufacturing technology for large-area modules. Thin-film technologies commonly require less or no high-cost crystalline Si. Many of the processes are high throughput and continuous (e.g., roll-to-roll); they usually do not involve high temperatures and, in some cases, do not require high-vacuum deposition equipment. Module fabrication, involving the interconnection of individual solar cells, is usually carried out as part of the film-deposition processes. The major systems are amorphous silicon, cadmium telluride,13 and copper indium diselenide14 (CIS) and related alloys (DOE, 2007h). Future directions include multijunction thin films aimed at significantly higher conversion efficiencies, better transparent conducting oxide electrodes, and thin polycrystalline silicon films. Dye-sensitized Solar Cells The dye-sensitized solar cell (O’Regan and Grätzel, 1991) has its foundation in photochemistry rather than in solid-state physics. In this device, also called the “Grätzel cell” after its Swiss inventor, organic dye molecules are adsorbed on a nanocrystalline titanium dioxide (TiO2) film, and the nanopores of the film are filled with a redox electrolyte. The dyes absorb solar photons to create an excited molecular state that can inject electrons into the TiO2. The electrons percolate through the nanoporous TiO2 film and are collected at a transparent electrode. The oxidized dye is reduced back to its initial state by accepting electrons from the redox relay via ionic transport from a metal counter-electrode; this completes the circuit and electrical power is delivered in the external circuit. Dye-sensitized solar cells are very attractive, because of the very low cost of the constituent materials (TiO2 is a common material used in paints and toothpaste) and the potential simplicity of their manufacturing process. Additionally, sensitized solar cells are tolerant to impurities, which allow ease in scaling up the production. Laboratory-scale devices of 11 percent efficiency have been demonstrated, but larger modules are typically less than half that efficient. Stability of the devices (e.g., dye materials and electrolyte) while maintaining high efficiency is an ongoing research issue (DOE, 2007k). Organic and Nanotechnology Solar Cells Organic semiconductors hold promise as building blocks for organic electronics, displays, and very low-cost solar cells. In an organic solar cell, light creates a bound electron-hole pair, called an exciton, which separates into an electron on one side and a hole on the other side of a material interface within the device. Polymers, dendrimers, small molecules and dyes, and inorganic nanostructures are materials that can be used 13 CdTe PVs require a small amount of semiconductor, and the production can be automated, which can increase its yield. 14 CIS has higher efficiency and has the capability to be made on a flexible substrate, but large-scale production might be limited to the availability of indium. 57

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION For energy storage, the energy density stored in gasoline is much greater than that storable in existing technologies for lithium-ion or flow batteries. Chemical Energy Storage Chemical energy storage refers to synthetic routes to producing fuels from energy resources. Depending on its nature, a fuel can subsequently be used for electricity production via fuel cells or used in conventional combustion systems. By far the simplest fuel to consider in this scenario is hydrogen, created according to the reaction: H2O + (renewable) energy → H2 + ½ O2. Regardless of how hydrogen is produced, the fuel must be stored, which is a daunting challenge. For example, compressing hydrogen to a pressure of 800 bar incurs an energy penalty of ~13 percent. At any pressure, the volumetric energy density of methane, a fuel more familiar to the electricity industry, is more than three times greater than that of hydrogen stored at an equal pressure (Bossel and Eliasson, 2003). Furthermore, after storage, hydrogen would be used either in a combustion process or in a fuel cell to provide electricity, both incurring additional efficiency penalties (~60 percent loss for combustion and ~30 percent loss for the fuel cell), resulting in a maximum “round-trip” efficiency of ~60 percent, assuming a 70 percent efficient fuel cell and 87 percent efficient compression, excluding energy penalties for the hydrogen production itself. With these caveats, it is nevertheless useful to consider methods of renewable hydrogen generation. If the energy input for splitting water is electricity, the reaction occurs simply by electrolysis. In the context of renewable electricity, generation is from solar, wind, or other renewable resources, and the electricity is then directed to a separate electrolysis cell. Small-scale electrolyzers are commercially available for the production of hydrogen for technical purposes. However, these systems’ overall efficiency, 65 to 70 percent, renders them unattractive for large-scale energy storage (Bossel and Eliasson, 2003). These systems require the use of platinum (Pt) at a quantity that can be estimated from the platinum used in state-of-the-art polymer electrolyte membrane fuel cells, which essentially operate in reverse relative to electrolyzers. A DOE target for platinum use is 1 g/kW. Storage for 46 GW average capacity (amounting to 10 percent of the U.S. average) would require 46 × 103 kg of platinum, which is a relatively small amount compared to both the known platinum reserves, ~ 7 × 106 kg, and the present rate of platinum consumption, ~ 250 × 103 kg per year (Wilburn and Bleiwas, 2004). Because of the inverse relationship between electrolyzers and fuel cells, there has been some research on electrochemical cells that could operate in either mode, particularly in the case of high-temperature ceramic electrolyte systems. These dual attributes would be attractive, because costs would be reduced as a result of the multi-functionality of the electrochemical cell, and the high-temperature operation would obviate the need for precious metal catalysts. In the case of solar energy, direct photo-electrochemical production of hydrogen is an attractive alternative to the two-step process (renewable energy → electricity → 82

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION fuel). In direct photo-electrochemical production, a semiconductor material, immersed in water, absorbs light, exciting electron-hole pairs across the band gap of the semiconductor. These electronic species are then available to perform reduction and oxidation reactions at the electrodes of the cell. As with the ambient-temperature electrolysis cell, developing robust and efficient, non-precious-metal catalysts remains a daunting challenge for this approach. However, the recognition that biological systems carry out such reactions (i.e., photosynthesis) using base-metal compounds as catalysts suggests that success could ultimately be achieved. The DOE is attempting to increase investment in this area, reflecting the potential offered by recent advances in this approach (e.g. , Muckerman et al., 2008). Yet another alternative for hydrogen production is the thermochemical cycle. In this approach, thermal energy, ideally solar-thermal energy, is the renewable input applied to a material that occurs in oxidized form at low temperatures and undergoes dissociation/reduction at high temperatures. The process of cycling between these two states under appropriate gaseous atmospheres releases the desired reduced chemical fuel. For example, if one considers the FeO/Fe3O4 system, the hydrogen production cycle can be described as Fe3O4 → 3FeO + ½ O2 (g) high temperature and 3FeO + H2O → Fe3O4 + H2 (g) low temperature. The success of the thermochemical approach relies fundamentally on the chemical thermodynamics of oxide stability. Rapid reaction kinetics and strong coupling of the solar radiation to the material for effective heating are also essential. There are no commercial activities in thermochemical fuel production, but there are ongoing large- scale demonstration plants at Sandia National Laboratories and at ETH Zurich. Alternatives to hydrogen fuel production are under consideration, because converting renewable energy to hydrogen fuel merely transfers the energy storage problem to a different part of the energy delivery infrastructure,. Alternatives typically employ biological processes to produce alcohols, alkanes, or other carbon-containing fuels, and can be considered advanced biomass approaches, such as production of biodiesel from algae. The few synthetic chemistry approaches investigated center largely on electrochemical reduction of CO2 to CO, whereby the combined carbon monoxide and hydrogen, or syngas, becomes the input in known industrial processes for the creation of a more suitable fuel. These approaches, still in the laboratory research stage, focus on chemical reaction pathways rather than potential scale-up to provide an energy solution. As components produced electrochemically, it is theoretically possible to react CO and H2 further to generate methane, a fuel familiar to the electricity industry and thus likely to have more immediate impact than penetration of renewable electricity. Because natural- gas peaking plants are often co-sited with solar and wind farms, direct production of methane using the output of the combustion power plant could provide a closed-loop system in which methane would not have to be transported. 83

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION Summary of Storage Potential Analysis of the future for the various storage technologies is beyond the scope of this panel, but some summary statements are in order. In the near term, diabatic CAES and various battery technologies, especially sodium sulfur batteries, have found initial applications in the electricity sector. In the longer term, when penetrations of renewables in the electricity sector might reach levels requiring energy storage, there may be a variety of approaches, including adiabatic CAES or the use of renewable energy in the production of chemical fuels. Advances in ultracapacitors and other short-term storage solutions may provide additional mechanisms to effectively integrate and stabilize intermittent resources. Energy storage is a system resource that should be operated for the overall benefit of the system. The greatest value of energy storage is realized when it is operated for the benefit of the entire system, and not dedicated to balancing any particular resource on the system. Storage tied to smart transmission and distribution grids would become a valuable component of any power system, and could provide numerous benefits to the system. Storage benefits the system without renewables, and renewables benefit the system without storage. The task is to manage variability with flexibility. Improved Grid Intelligence⎯the Smart Grid The architecture needed to improve integration of renewables into the electricity grid would incorporate a variety of technologies, such as advanced sensors; smart meters (net metering, turn-on/turn-off capability, and the capability to enable time-of-day pricing); power converters, conditioners, and other power-quality technologies; source and load controls; improved software, including forecasting and operations models; and storage technologies (Kroposki, 2007). Most of these technologies are part of the broad initiative to improve the intelligence of the modern grid.33 The objectives to meet in modernizing the electricity grid go beyond increasing intermittent renewables, and include improving security and power quality and creating a more efficient, adaptive electricity system. Demonstrations are under way in several U.S. cities (e.g., Boulder, Colorado), but widespread deployment is expected to take decades.34 More details on the objectives and technologies involved in creating a future electricity grid with increased capacity and intelligence are presented in the upcoming report of the Committee on America’s Energy Future (NAS-NAE-NRC, 2009b). 33 The term “Smart Grid” has often been used to describe this initiative. The Smart Grid may be described as the overlaying of a unified electronic control systems and two-way communication over the entire power delivery infrastructure. Smart Grid capabilities optimize power supply and delivery, minimize loss, and enable maximum use of electricity generation resources, energy efficiency, and demand responses. However, this term suffers from overuse and multiple interpretations. The panel instead uses the improved term “grid intelligence” to refer to the collection of technologies needed to improve the integration of renewables into. 34 EISA 2007 authorized the Smart Grid Advisory Committee and Task Force through 2020. An earlier (2003) DOE plan was called Grid2030; the intention was to have 100 percent of electricity running through a smart grid by 2030. 84

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION A truly intelligent modern grid would anticipate the fluctuations in the power output from intermittent renewable energy sources and maintain absolute supply/demand equivalency on a given transmission or distribution circuit, while requiring less compensating backup power and storage capacity. Instantaneous electronic control of the grid would allow each transmission line to operate at a higher load factor without risking thermal overload than is now feasible on the electromechanically controlled transmission system. This level of coordinated control would require improved communications and seamless connectivity, or interoperability,35 which would make the grid a dynamic, interactive infrastructure for the real-time exchange of power and information. Open connectivity architecture would create a plug-and-play environment that would securely network grid components and operators. The current lack of uniform interconnection and operations codes and standards as well as the acceptance of standardized open communications architecture is restricting the timely implementation of the modern grid. A system-wide integrated cyber security capability is also an important dimension of this communications architecture. The Smart Grid’s emphasis today is primarily on creating interstate high-voltage transmission capabilities to facilitate bulk wind power access. While important, transmission is only one element of the nationwide grid modernization effort needed to realize the potential benefits of renewable energy. The electronic modernization of the local electricity distribution network is equally essential to incorporating distributed renewable energy technologies such as photovoltaics and wind power. One critical objective of smart distribution grids is to enable the seamless, uninterruptible balancing of electricity supply and demand, which could allow distributed renewable power generation to be broadly dispatchable. Dispatchability would improve intermittent renewables’ compatibility with the reliability and operational requirements of the bulk power system. The result could help transform buildings into power plants and provide a more reliable, efficient and clean electricity supply system. Advanced Metering Advanced metering—the use of electricity meters that provide detailed consumption profiles⎯is one technology for improving the intelligence of the grid that would be particularly important to increasing the use of distributed renewables. Unlike conventional metering, advanced metering would couple the cost of electricity generation with the price to the consumer. In the context of renewables integration, the ability to do time-of-day pricing and net metering would better enable the deployment of renewables, especially solar PV. Such meters also could communicate real-time information to the consumer for billing and pricing purposes. Because solar PV generation peaks close to the late-afternoon price peak, meters allowing time-of-day pricing could improve the cost-competitiveness of solar PV at the consumer end. Advanced metering also helps to create incentives to use energy at off-peak times when possible, thereby reducing demands on the transmission and distribution systems. Chapter 4 discusses the use of real-time pricing to encourage the development of renewables. 35 Seamless, end-to-end connectivity of the hardware and software throughout the transmission and distribution system to the electrical energy source. 85

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION Furthermore, advanced metering technologies would enable net metering for those with on-site renewable generation. Net metering improves the integration into the grid of distributed renewable resources such as solar PV installed at residential and commercial facilities. It measures both the consumption of electricity and the excess energy produced on-site, and at least partly credits the consumer for excess generation produced by consumer-owned solar PV or other renewable electricity technologies. Software/Modeling Support New grid operating tools are also needed to incorporate renewable energy resources, including operating models and system impact algorithms that address the transient behavior of renewable energy; improved operators’ visualization techniques and new training methodologies; and advanced simulation tools that can provide an accurate understanding of grid behavior. These grid operating tools would also assist system planners in designing reliable power systems for this new environment. Better forecasting algorithms would allow better use of temporally varying resources such as wind energy. The objective of this work is to improve the forecasting of wind and its use in electricity markets (Ahlstrom et al., 2005; Hawlins and Rothleder, 2006; Smith, 2007). Reactive Dynamic Power The demand that some renewables place on ancillary services, such as reactive power and dynamic voltage control, also must be considered.. Reactive power is the portion of electricity that establishes and maintains the electric and magnetic fields of alternating current (AC) equipment. Because wind and solar power produce direct current (DC), reactive power must be provided in the DC-to-AC conversion process, a requirement that is complicated by the variable/intermittent nature of these renewable energy sources: the reactive power must be equally dynamic to keep pace. Many early wind machines were induction generator wind turbines with a constant frequency and so required reactive power to be supplied from the grid. While newer machines have solved this problem, voltage stability remains an issue. The European Transmission System Operators (ETSO) recently completed a study on the ancillary services required by wind power as the amount of installed wind capacity in Europe increased from 41 GW in 2005 to an expected 67 GW in 2008 (ETSO, 2007). In particular, the ETSO study looked at the effects of variable power output on the electricity grid and the ability of various wind turbine types to provide system service needed for the stable operation of an electricity grid. Another study describes technologies used to provide reactive power for a large wind farm and the interactions of the wind farm, reactive power compensation, and the power system network (Muljadi et al., 2004). 86

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION FINDINGS The most critical elements of the panel’s findings on renewable electricity generation technologies are highlighted below. Over the first time frame through 2020, wind, solar photovoltaics and concentrating solar power, conventional geothermal, and biopower technologies are technically ready for accelerated deployment. During this period, these technologies could potentially contribute a much greater share (up to ~10 percent of electricity generation) of the U.S. electricity supply than they do today. Other technologies, including enhanced geothermal systems that mine the heat stored in deep low- permeability rock and hydrokinetic technologies that tap ocean tidal currents and wave energy, require further development before they can be considered viable entrants into the marketplace. The costs of already-developed renewable electricity technologies will likely be driven down through incremental improvements in technology, “learning curve” technology maturation, and manufacturing economies of scale. Despite short-term increases in cost over the past couple of years, in particular for wind turbines and solar photovoltaics, there have been substantial long-term decreases in the costs of these technologies, and recent cost increases due to manufacturing and materials shortages will be reduced if sustained growth in renewable sources spurs increased investment in them. In addition, support for basic and applied research is needed to drive continued technological advances and cost reductions for all renewable electricity technologies. In contrast to fossil-based or nuclear energy, renewable energy resources are more widely distributed, and the technologies that convert these resources to useful energy must be located at the source of the energy. Further, extensive use of intermittent renewable resources such as wind and solar power to generate electricity must accommodate temporal variation in the availability of these resources. This variability requires special attention to system integration and transmission issues as the use of renewable electricity expands. Such considerations will become especially important at greater penetrations of renewable electricity in the domestic electricity generation mix. A contemporaneous, unified intelligent electronic control and communications system overlaid on the entire electricity delivery infrastructure would enhance the viability and continued expansion of renewable electricity in the period from 2020 to 2035. Such improvements in the intelligence of the transmission and distribution grid could enhance the whole electricity system’s reliability and help facilitate integration of renewable electricity into that system, while reducing the need for backup power to support the enhanced utilization of renewable electricity. In the third time period, 2035 and beyond, further expansion of renewable electricity is possible as advanced technologies are developed, and as existing technologies achieve lower costs and higher performance with the maturing of the technology and an increasing scale of deployment. Achieving a predominant (i.e., >50 percent) penetration of intermittent renewable resources such as wind and solar into the electricity marketplace, however, will require technologies that are largely unavailable or not yet developed today, such as large-scale and distributed cost-effective energy storage and new methods for cost-effective, long-distance electricity transmission. Finally, there might be further consideration of an integrated hydrogen and electricity transmission 87

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION Jones, A.T., and W. Finley. 2003. Recent developments in salinity gradient power. Pp. 2284-2287 in OCEANS 2003: Celebrating the Past, Teaming Toward the Future. Marine Technology Society, Columbia, Md. King, D.L., W.E. Boyson, and J.A. Mratochvil. 2004. Photovoltaic Array Performance Model. Sandia National Laboratories, Photovoltaic System R&D Department, Albuquerque, N.M. Kroposki, B. 2007. Renewable Energy Interconnection and Storage. Presentation at the First Meeting of the Panel on Electricity from Renewables, September, 18, 2008. Washington, D.C. Mancini, T., P. Heller, B. Bulter, B. Osborn, S. Wolfgang, G. Vernon, R. Buck, R. Diver, C. Andraka, and J. Moreno. 2003. Dishing Stirling systems: An overview of development and status. Journal of Solar Energy Engineering 125:135-151. McKenna. 2005. Miles, A.C. 2008. Hydropower at the Federal Energy Regulatory Commission. Presentation at the Third Meeting of the Panel on Electricity from Renewables, January 16, 2008. Washington, D.C. Mills, D., P. Le Lievre, and G.L. Morrison. 2004. Lower temperature approach for very large solar power plants. Proceedings of the 12th International Symposium on Solar Power and Chemical Energy Systems (SolarPACES ’04), Oaxaca, Mexico. Available at http://www.ausra.com/pdfs/LowerTempApproach_Mills_2006.pdf. Minerals Management Service. 2006. Wave Energy Potential on the U.S. Outer Continental Shelf, Technology White Paper. Renewable Energy and Alternate Use Program, U.S. Department of the Interior, Washington, D.C. MIT (Massachusetts Institute of Technology). 2006. The Future of Geothermal Energy: Impact of Enhanced Geothermal Systems (EGS) on the United States in the 21st Century. Cambridge, Mass. Muckerman, J.T., D.E. Polyansky, T. Wada, K. Tanaka, and E. Fujita. 2008. Water oxidation by a ruthenium complex with noninnocent quinone ligands: Possible formation of an O−O bond at a low oxidation state of the metal. Inorganic Chemistry 47(6):1787-1802. Muljadi, E., C.P. Butterfield, R. Yinger, and H. Romanowitz. 2004. Energy storage and reactive power compensator in a large wind farm. Paper presented at 42nd AIAA Aerospace Sciences Meeting and Exhibit, January 5-8, 2004, Reno, Nevada. AIAA 2004-352. American Institute of Aeronautics and Astronautics, Reston, Va. Available at http://pdf.aiaa.org/preview/CDReadyMASM04_665/PV2004_352.pdf. NAS-NAE-NRC (National Academy of Sciences-National Academy of Engineering- National Research Council). 2009a. Liquid Transportation Fuels from Coal and Biomass: Technological Status, Costs, and Environmental Impacts. The National Academies Press, Washington, D.C. NAS-NAE-NRC. 2009b. America’s Energy Future: Technology and Transformation. The National Academies Press, Washington, D.C. NREL (National Renewable Energy Laboratory). 2008. About Geothermal Electricity. Golden, Colo. Available at http://www.nrel.gov/geothermal/geoelectricity.html. NYISO (New York Independent System Operator). 2008. Forecasts Sufficient Electricity Supply for Summer 2008. NYISO Press Release. Rensselaer, N.Y. 90

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PREPUBLICATION COPY—SUBJECT TO FURTHER EDITORIAL CORRECTION Wiltsee, G. 2000. Lessons Learned from Existing Biomass Power Plants. National Renewables Energy Laboratory, Golden, Colo. February. Available at http://www.nrel.gov/docs/fy00osti/26946.pdf. 92