Appendix B
Consolidated Exhaust Gas Characteristics for the JACADS and TOCDF Baseline Incineration Systems
Emissions test results were originally reported in the units required by the cognizant agencies at the time. Over time, the reporting units have changed and are now different for each facility. Consequently, direct comparisons and meaningful summaries require converting results into common units. The information in this appendix is standardized to Environmental Protection Agency (EPA) reference conditions (68°F for temperature; 760 mm Hg for pressure; 0 percent for moisture; and 7 percent for residual oxygen content) and conventional EPA regulatory units (ppmdv for gaseous criteria pollutants and acid gases; mg/dsm 3 for particulates; μg/dsm3 for individual elements; and ng/dsm3 at 7 percent O2 for trace organics). In developing this appendix, the committee reviewed the underlying laboratory and field reports to verify the overall accuracy of data reduction and quality assurance warnings. Reported results were compared to database values prior to standardization to eliminate transcription errors and identify errors in data reduction.
TABLE B-1 Exhaust Gas Characteristics for the JACADS and TOCDF Baseline Incineration Systems
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
Exhaust Gas Characteristics |
||||||||||
Temperature (ºF) |
|
155 |
|
|
155 |
180 |
208.23 |
280 |
100% |
|
Flow rate (dsft3/min) |
|
149 |
|
|
149 |
2,275 |
6,043 |
11,493 |
100% |
|
Oxygen (%) |
|
162 |
|
|
162 |
1.2 |
12.955 |
15.1 |
100% |
|
Moisture (%) |
|
158 |
|
|
158 |
31.3 |
40.543 |
56.2 |
100% |
|
Combustion Quality Indicators (ppmdv) |
||||||||||
Carbon monoxide |
|
35 |
0 |
|
35 |
2 |
39 |
62 |
100% |
|
Total hydrocarbons as carbon |
|
20 |
0 |
|
20 |
2.6 |
6.6 |
9.0 |
100% |
|
Chemical Agents (ng/dsm3) |
||||||||||
GB (Sarin) |
|
28 |
28 |
3.6 |
0 |
|
|
|
0% |
0.0006 |
HD (mustard gas) |
|
12 |
12 |
230 |
0 |
|
|
|
0% |
0.035 |
VX |
|
0 |
0 |
|
0 |
|
|
|
|
|
Particulates |
||||||||||
PM (gr/dsm3) |
|
103 |
0 |
|
103 |
0.9 |
14.7 |
50 |
100% |
|
PM (gr/dscf) |
|
103 |
103 |
|
103 |
0.0004 |
0.006 |
0.022 |
100% |
|
CAA Acid Gas HAPs (ppmdv) |
||||||||||
Hydrogen chloride |
|
60 |
44 |
|
16 |
0.01 |
11 |
44.16 |
27% |
11,172 |
Chlorine gas |
|
6 |
3 |
(0.03) |
0 |
|
|
|
0% |
(30.00) |
CAA Trace Element HAPs (μg/dsm3) |
||||||||||
Arsenic |
(2.3) |
49 |
37 |
(0.02) |
12 |
1 |
10 |
42 |
24% |
|
Beryllium |
(4.2) |
35 |
0 |
|
2 |
0.008 |
0.008 |
0.008 |
6% |
|
Cadmium |
(5.6) |
35 |
7 |
(0.20) |
28 |
0 |
6 |
50 |
80% |
|
Cobalt |
|
9 |
0 |
|
9 |
0.08 |
0.23 |
0.8 |
100% |
|
Chromium (total) |
1,000,000 |
46 |
0 |
|
41 |
0.22 |
7.4 |
56 |
89% |
|
Chromium (hexavalent) |
(0.83) |
20 |
13 |
(0.3) |
7 |
0.34 |
1.8 |
4.2 |
35% |
|
Mercury |
300 |
43 |
0 |
|
26 |
0.25 |
7.1 |
25 |
60% |
0.9 |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
CAA Trace Element HAPs (μg/dsm3) |
||||||||||
Manganese |
|
30 |
0 |
|
30 |
0.43 |
233 |
2,105 |
100% |
|
Phosphorus |
|
12 |
0 |
|
12 |
84 |
1,508 |
5,934 |
100% |
|
Antimony |
300 |
35 |
28 |
(0.11) |
7 |
0.16 |
1.9 |
5.4 |
20% |
|
Selenium |
|
24 |
0 |
|
6 |
0.16 |
6.2 |
15 |
25 % |
|
Other Trace Elements (μg/dsm3) |
||||||||||
Aluminum |
|
9 |
0 |
|
9 |
82 |
98 |
125 |
100% |
|
Barium |
50,000 |
42 |
0 |
|
34 |
1 |
14 |
86 |
81% |
|
Boron |
|
12 |
0 |
|
12 |
0.41 |
36 |
257 |
100% |
|
Copper |
|
24 |
0 |
|
19 |
0.20 |
49 |
294 |
79% |
|
Potassium |
|
20 |
0 |
|
14 |
19 |
1,253 |
5,940 |
70% |
|
Nickel |
(42) |
19 |
0 |
|
17 |
0.16 |
33 |
216 |
89% |
|
Lead |
90 |
49 |
0 |
|
34 |
0.16 |
122 |
1,704 |
69% |
|
Tin |
|
24 |
0 |
(14) |
18 |
2.0 |
122 |
692 |
75% |
|
Thallium |
|
35 |
35 |
(0.1) |
0 |
|
|
|
0% |
|
Vanadium |
|
9 |
9 |
(0.81) |
0 |
|
|
|
0% |
|
Zinc |
|
39 |
0 |
|
35 |
7.5 |
119 |
488 |
90% |
|
CAA Trace Organic HAPs (ng/dsm3) |
||||||||||
4-aminobiphenyl |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
Aniline |
(14,000) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(2) |
Benzene |
(12,000) |
39 |
0 |
|
23 |
0.10 |
17,401 |
99,286 |
59% |
5 |
Benzidene |
(0.15) |
12 |
12 |
(9,994) |
0 |
0% |
|
|
|
(1) |
Bromoform |
|
39 |
0 |
|
26 |
0.0002 |
6,234 |
18,230 |
67% |
1 |
Bromomethane |
800 |
21 |
14 |
(2,904) |
7 |
3,690 |
5,320 |
6,775 |
33% |
1 |
Butadiene |
|
18 |
18 |
(11,564) |
0 |
|
|
|
0% |
(5) |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
CAA Trace Organic HAPs (ng/dsm3) |
||||||||||
Carbon tetrachloride |
(670) |
26 |
18 |
(2,219) |
8 |
2,823 |
26,655 |
86,623 |
31% |
4 |
Chloroform |
(430) |
33 |
0 |
|
21 |
0.0001 |
8,069 |
42,304 |
64% |
2 |
Carbon disulfide |
200,000 |
29 |
23 |
(812) |
6 |
14,020 |
25,127 |
47,170 |
21% |
8 |
Dibenzofuran |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
1,3-dichlorobenzene |
10,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
1,4-dichlorobenzene |
10,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
3,3-dichlorobenzidine |
|
12 |
12 |
(10,974) |
0 |
|
|
|
0% |
(1) |
Trans-1,3-dichloropropene |
(0.029) |
15 |
15 |
(2,219) |
0 |
|
|
|
0% |
(0.5) |
3,3-dimethylbenzidene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
2,4-dinitrotoluene |
(110) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.8) |
Ethlylene dibromide |
(0.45) |
12 |
12 |
(2,336) |
0 |
|
|
|
0% |
(0.3) |
Ethylbenzene |
|
26 |
19 |
(403) |
7 |
521 |
2,016 |
4,250 |
27% |
0.5 |
Ethyl chloride |
|
18 |
18 |
(1,958) |
0 |
|
|
|
0% |
(0.7) |
Bis(2-ethylhexyl)phthalate |
(42,000) |
15 |
10 |
(6,178) |
5 |
10,723 |
94,214 |
272,641 |
33% |
6 |
N-hexane |
|
21 |
17 |
(1,958) |
4 |
2,336 |
2,523 |
2,682 |
19% |
0.7 |
Hexachlorobenzene (total) |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Hexachlorobutadiene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Hexachlorocyclopentadiene |
5,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Hexachloroethane |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Isophorone |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Methyl ethyl ketone |
80,000 |
24 |
20 |
(10,572) |
4 |
69,856 |
78,682 |
92,667 |
17% |
26 |
Methylene chloride |
(2,400) |
39 |
15 |
(0.00006) |
18 |
0.0004 |
205,026 |
3,088,889 |
55% |
58 |
2-methylphenol [o-cresol] |
50,000 |
15 |
12 |
(6,074) |
3 |
77,222 |
164,605 |
264,762 |
20% |
37 |
Naphthalene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Nitrobenzene |
800 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
4-nitrophenol |
|
12 |
12 |
(7,722) |
0 |
|
|
|
0% |
(1) |
Styrene |
|
35 |
19 |
(1,283) |
16 |
3,947 |
42,283 |
514,734 |
46% |
17 |
1,1,2,2-tetrachloroethane |
(170) |
27 |
25 |
(1,283) |
2 |
2,206 |
2,206 |
2,206 |
7% |
0.3 |
1,1,2-trichloroethane |
(630) |
18 |
18 |
(1,958) |
0 |
|
|
|
0% |
(0.4) |
Tetrachloroethylene |
(21,000) |
6 |
3 |
(3,349) |
3 |
4,277 |
16,135 |
26,476 |
50% |
2 |
Toluene |
300,000 |
36 |
0 |
|
24 |
0.00 |
5,960 |
28,234 |
67% |
0.8 |
Vinyl bromide |
|
9 |
9 |
(9,789) |
0 |
|
|
|
0% |
(2) |
Vinylidene chloride |
|
3 |
3 |
(2,219) |
0 |
|
|
|
0% |
(0.6) |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μtg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
Caa Trace Organic HAPs (ng/dsm3) |
||||||||||
Methyl chloride |
|
12 |
9 |
(3,527) |
3 |
29,938 |
1,135,218 |
3,088,889 |
25% |
541 |
Vinyl chloride |
(1,400) |
26 |
18 |
(415) |
8 |
996 |
5,325 |
21,502 |
31% |
2 |
Vinyl acetate |
|
24 |
22 |
(1,324) |
2 |
1,497 |
1,497 |
1,497 |
8% |
0.4 |
Xylene(m & p) |
80,000 |
22 |
17 |
(434) |
5 |
456 |
2,910 |
5,169 |
23% |
0.7 |
Xylene(o) |
80,000 |
22 |
0 |
|
6 |
934 |
2,066 |
3,676 |
27% |
0.5 |
Pentachlorophenol (total) |
30,000 |
12 |
12 |
(30,370) |
0 |
|
|
|
0% |
(3) |
Phenol |
30,000 |
12 |
7 |
(6,765) |
5 |
7,125 |
9,632 |
13,440 |
42% |
2 |
1,4-benzenediamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
1,2,4-trichlorobenzene |
20,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.8) |
4-methylphenol [p-cresol] |
50,000 |
3 |
1 |
(6,178) |
2 |
51,323 |
943,503 |
1,835,683 |
67% |
210 |
3-methylphenol [m-cresol] |
50,000 |
3 |
0 |
|
2 |
2,780 |
12,422 |
22,063 |
67% |
3 |
Dimethylphthalate |
|
9 |
0 |
|
8 |
9,953 |
30,987 |
99,942 |
89% |
4 |
Di-n-butylphthalate |
100,000 |
3 |
0 |
|
3 |
10,811 |
31,013 |
66,190 |
100% |
3 |
Cis-1,3-dichloropropene |
(0.029) |
3 |
3 |
(2,336) |
0 |
|
|
|
0% |
(0.5) |
Other Trace Organics (ng/dsm3) |
||||||||||
Acenaphthene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
Acenaphthylene |
|
12 |
0 |
|
1 |
1,000 |
1,000 |
1,000 |
8% |
0.05 |
Acetone |
|
39 |
|
|
28 |
0.001 |
32,851 |
110,317 |
72% |
14 |
Acetophenone |
100,000 |
12 |
11 |
(6,074) |
1 |
6,828 |
6,828 |
6,828 |
8% |
1 |
2-acetylaminofluorene |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(7) |
3-amino-9-ethycarbazole |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(7) |
Anthracene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.8) |
Aramite |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.4) |
Benzoic acid |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(12) |
Benz(a)anthracene |
(11) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Bromodichloromethane |
|
21 |
12 |
(2,937) |
9 |
3,271 |
6,968 |
13,440 |
43% |
1 |
Benzo(b)fluoranthene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Benzo(j)fluoranthene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Benzo(k)fluoranthene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Benzo(g,h,i)perylene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Benzo(a)pyrene |
(3) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Bromodichloromethane |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μtg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
Other Trace Organics (ng/dsm3) |
||||||||||
Benzyl alcohol |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Benzaldehyde |
|
12 |
10 |
(6,074) |
2 |
9,438 |
19,791 |
30,145 |
17% |
4 |
Benzenethiol |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(13) |
Biphenyl |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
Bromophenyl-phenylether(4) |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Butylbenzylphthalate |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Cis-1,4-dichloro-2-butene |
|
21 |
21 |
(1,958) |
0 |
|
|
|
0% |
(0.4) |
Trans-1,4-dichloro-2-butene |
|
12 |
12 |
(2,336) |
0 |
|
|
|
0% |
(0.4) |
Cis-1,3-dichloropropene |
(2.2) |
31 |
18 |
(403) |
13 |
478 |
140,561 |
898,154 |
42% |
30 |
4-chloroaniline |
|
9 |
9 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Bis(2-chloroethoxy)methane |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(2) |
Bis(2-chloroethyl)ether |
(0.16) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
2,2-oxybis(1-chloropropane) |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(2) |
Chlorobenzilate |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.4) |
4-chloro-3-methylphenol |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
1-chloronaphthalene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
2-chloronaphthalene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
2-chlorophenol |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
4-chlorophenyl-phenylether |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
Chrysene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
2-chloropropane |
|
12 |
12 |
(2,336) |
0 |
|
|
|
0% |
(0.7) |
Chlorobenzenes (total) |
|
29 |
22 |
(434) |
7 |
539 |
2,519 |
3,942 |
24% |
(0.09) |
4,4-DDE |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(5) |
Diallate |
|
12 |
12 |
(11,681) |
0 |
|
|
|
0% |
(1) |
Dibenz(a,h)anthracene |
(0.71) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.52) |
Dibromochloropropane |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(6) |
di-n-butyl phthalate |
100,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
1,2-dichlorobenzene |
10,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
2,4-dichlorophenol |
3,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
2,6-dichlorophenol |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
Dichloromethane |
|
9 |
3 |
(1,958) |
6 |
7,201 |
9,353 |
11,797 |
67% |
3 |
Dibromomethane |
|
18 |
18 |
(2,219) |
0 |
|
|
|
0% |
(0.3) |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
Other Trace Organics (ng/dsm3) |
||||||||||
1,1-dichloroethene |
|
25 |
25 |
(415) |
0 |
|
|
|
0% |
(0.1) |
1,2-dichloroethene |
|
12 |
12 |
(1,958) |
0 |
|
|
|
0% |
(0.5) |
1,2-dichloropropane |
|
27 |
25 |
(1,103) |
2 |
1,047,846 |
1,047,846 |
1,047,846 |
7% |
223 |
1,1-dichloroethane |
(380) |
18 |
18 |
(1,958) |
0 |
|
|
|
0% |
(0.5) |
1,2-dichloroethane |
(200) |
15 |
15 |
(2,219) |
0 |
|
|
|
0% |
(0.5) |
Dihydrosafrole |
|
12 |
12 |
(7,722) |
0 |
|
|
|
0% |
(1) |
Diethylphthalate |
800,000 |
15 |
12 |
(6,074) |
3 |
66,190 |
400,164 |
933,286 |
20% |
43 |
P-dimethylaminoazobenzene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
7,12-dimethylbenzo(a)anthracene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
a,a-dimethylphenethyl-amine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
2,4-dimethylphenol |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Dimethylphthalate |
|
12 |
11 |
(5,840) |
1 |
41,456 |
41,456 |
41,456 |
8% |
5 |
1,3-dinitrobenzene (m,o,p) |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
4,6-dinitro-2-methylphenol |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
2,4-dinitrophenol |
|
12 |
12 |
(30,370) |
0 |
|
|
|
0% |
(4) |
2,6-dinitrotoluene |
|
12 |
9 |
(6,074) |
3 |
|
|
|
25% |
(0.8) |
Dioxathion |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(3) |
Di-n-octylphthalate |
|
15 |
14 |
(5,988) |
1 |
48,540 |
48,540 |
48,540 |
7% |
4 |
1,2-diphenylhydrazine |
(4.5) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Diphenylamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
Ethylmethanosulfonate |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Ethylparathion |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(12) |
Fluoranthene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
Fluorene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
Freon 12 |
|
12 |
12 |
(2,336) |
0 |
|
|
|
0% |
(0.5) |
Freon 113 |
|
18 |
18 |
(1,958) |
0 |
|
|
|
0% |
(0.3) |
2-hexanone |
|
27 |
25 |
(600) |
2 |
3,500 |
3,500 |
3,500 |
7% |
0.8 |
Heptachlor |
(7.7) |
12 |
12 |
(44,800) |
0 |
|
|
|
0% |
(3) |
Hexachlorophene |
300 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.4) |
Hexachloropropene |
|
12 |
12 |
(7,095) |
0 |
|
|
|
0% |
(0.7) |
Indeno(1,2,3-cd)pyrene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Isosafrole |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
Methapyrilene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
Other Trace Organics (ng/dsm3) |
||||||||||
4-methyl-2-pentanone |
|
24 |
23 |
(1,283) |
1 |
10,370 |
10,370 |
10,370 |
4% |
2 |
Methoxyclor |
50,000 |
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(4) |
3-methylcholanthrene |
(3.7) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.5) |
Methylmethanesulfonate |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
3,4-methylphenanthrene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.8) |
2-methylnaphthalene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
2-methyl-5-nitroaniline |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(11) |
1-naphthylamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
2-naphthylamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
( 1 ) |
2-nitrophenol |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
4-nitroquinoline-1-oxide |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
N-nitrozo-di-n-butylamine ng/dsm3 |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
N-nitroso-di-n-propylamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
N-nitrosodiethylamine |
(0.23) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
N-nitrosodimethylamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(2) |
N-nitrophenylamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
1,4-naphthoquinone |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
5-nitroacenaphthene |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(7) |
2-nitroaniline |
|
12 |
12 |
(35,474) |
0 |
|
|
|
0% |
(6) |
3-nitroaniline |
|
12 |
12 |
(35,474) |
0 |
|
|
|
0% |
(6) |
4-nitroaniline |
|
12 |
12 |
(35,474) |
0 |
|
|
|
0% |
(6) |
2-propanol |
|
12 |
12 |
(230,226) |
0 |
|
|
|
0% |
(92) |
1,1,1,2-tetrachloroethane |
|
12 |
12 |
(2,336) |
0 |
|
|
|
0% |
(0.5) |
Trans-1,2-dichloroethane |
(38) |
15 |
15 |
(1,958) |
0 |
|
|
|
0% |
(0.5) |
Trichloroethane |
|
3 |
3 |
(2,219) |
0 |
|
|
|
0% |
(0.4) |
1,1,1-trichloroethane |
|
31 |
26 |
(403) |
5 |
479 |
9,131 |
20,416 |
16% |
2 |
Tetrachloroethene |
|
31 |
22 |
(403) |
9 |
428 |
2,814 |
8,541 |
29% |
0.4 |
Trichlorofluoromethane |
300,000 |
18 |
18 |
(1,958) |
0 |
|
|
|
0% |
(0.3) |
1,1,2-trichloroethene |
|
7 |
6 |
(0) |
1 |
0.0003 |
0.0003 |
0.0003 |
14% |
0.00000005 |
Trichloroethylene |
(7,700) |
15 |
15 |
(1,958) |
0 |
|
|
|
0% |
(0.4) |
1,2,3-chloropropane |
|
3 |
3 |
(3,349) |
0 |
|
|
|
0% |
(1) |
Trans-1,3-dichloropropene |
(0.029) |
15 |
15 |
(2,219) |
0 |
|
|
|
0% |
(0.5) |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
Other Trace Organics (ng/dsm3) |
||||||||||
Bromoethane |
|
9 |
9 |
(11,564) |
0 |
|
|
|
0% |
(3) |
N-nitrosomethylethylamine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(2) |
N-nitrosomorpholine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
N-nitrosopiperidine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
N-nitrosopyrrolidine |
(16) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(2) |
5-nitro-o-toluidine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Pentachlorobenzene (total) |
800 |
12 |
12 |
(7,095) |
0 |
|
|
|
0% |
(0.7) |
Penthachloroethane |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
Pentachloronitrobenzene |
(140) |
12 |
12 |
(30,370) |
0 |
|
|
|
0% |
(3) |
Phenacetin |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.8) |
Phenanthrene |
|
12 |
11 |
(6,074) |
1 |
8,752 |
8,752 |
8,752 |
8% |
1 |
2-picoline |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(2) |
Pronamide |
(2,200) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.6) |
Pyrene · |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
Pyridine |
1,000 |
12 |
12 |
(11,681) |
0 |
|
|
|
0% |
(4) |
Quinoline |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(11) |
Safrole |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.9) |
1,2,4,5-tetrachlorobenzene |
300 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
2,3,4,6-tetrachlorophenol |
30,000 |
12 |
12 |
(30,370) |
0 |
|
|
|
0% |
(3) |
P-toludine |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(14) |
2-toluidine |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(1) |
Tributylamine |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(8) |
2,4,5-trichlorophenol |
100,000 |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
2,4,6-trichlorophenol |
(1,800) |
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
0,0,0-triethylphosphorothioate |
|
12 |
12 |
(60,739) |
0 |
|
|
|
0% |
(10) |
1,3,5-trinitrobenzene |
|
12 |
12 |
(6,074) |
0 |
|
|
|
0% |
(0.7) |
Chloromethane |
28,000 |
12 |
9 |
(3,349) |
3 |
705,692 |
786,818 |
904,603 |
25% |
375 |
Total xylene |
80,000 |
3 |
2 |
(1,283) |
1 |
1,986 |
1,986 |
1,986 |
33% |
0.4 |
Trans-l,2-dichloroethylene |
|
3 |
3 |
(2,336) |
0 |
|
|
|
0% |
(0.6) |
N,n'-diisopropylcarbodiimide |
|
6 |
6 |
(52,000) |
0 |
|
|
|
0% |
(10) |
Diisopropylmethylphosphonate |
|
6 |
6 |
(60,739) |
0 |
|
|
|
0% |
(10) |
1,2,3-trichlorophenol |
|
6 |
6 |
(2,000) |
0 |
|
|
|
0% |
(0.2) |
|
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a |
Total Runs |
Nondetects Lower than Lowest Detected Valuesb |
Detected Values Only |
Detected Values |
Average or DL ppbdv |
||||
Values are at 7% O2 Unless Otherwise Specified |
μg/m3 |
N |
N |
Detection Limit |
N |
Minimum |
Average |
Maximum |
|
|
Polychlorinated Dibenzo-P-Dioxins and Dibenzo Furans (ng/dsm3) |
||||||||||
2,3,7,8-tetrachlorodibenzo-p-dioxin |
(0.00022) |
32 |
31 |
(0.0002) |
1 |
0.002 |
0.002 |
0.002 |
3% |
0.0000002 |
Tetrachlorodibenzo-p-dioxins (total) |
|
47 |
13 |
(0.0004) |
36 |
0.001 |
0.110 |
0.968 |
72% |
0.000008 |
2,3,7,8-tetrachlorodibenzofuran |
|
32 |
9 |
(0.002) |
26 |
0.003 |
0.015 |
0.066 |
74% |
0.000001 |
Tetrachlorodibenzofurans (total) |
|
50 |
0 |
|
51 |
0.004 |
0.208 |
1.244 |
96% |
0.00002 |
1,2,3,7,8-pentachlorodibenzo-p-dioxin |
|
32 |
32 |
(0.001) |
0 |
|
|
|
0% |
(0.0000001) |
Pentachlorodibenzo-p-dioxins (total) |
|
43 |
28 |
(0.001) |
15 |
0.005 |
0.181 |
0.877 |
33% |
0.00001 |
1,2,3,7,8-pentachlorodibenzofuran |
|
32 |
30 |
(0.001) |
2 |
0.054 |
0.064 |
0.074 |
6% |
0.000005 |
2,3,4,7,8-pentachlorodibenzofuran |
|
32 |
29 |
(0.0005) |
3 |
0.041 |
0.086 |
0.159 |
9% |
0.000006 |
Pentachlorodibenzofurans (total) |
|
47 |
17 |
(0.001) |
30 |
0.004 |
0.357 |
1.815 |
60% |
0.00003 |
1,2,3,4,7,8-hexachlorodibenzo-p dioxin |
(0.0077) |
32 |
32 |
(0.0002) |
0 |
|
|
|
0% |
|
(0.00000001) |
|
|
|
|
|
|
|
|
|
|
1,2,3,6,7,8-hexachlorodibenzo p-dioxin |
(0.0077) |
32 |
32 |
(0.0001) |
0 |
|
|
|
0% |
|
(0.00000001) |
|
|
|
|
|
|
|
|
|
|
1,2,3,7,8,9-hexachlorodibenzo-p dioxin |
(0.0077) |
32 |
31 |
(0.0002) |
6 |
0 |
0.0211 |
0.1269 |
17% |
0.000001 |
Hexachlorodibenzo-p-dioxins (total) |
|
47 |
28 |
(0.0002) |
19 |
0.006 |
0.528 |
2.860 |
38% |
0.00003 |
1,2,3,4,7,8-hexachlorodibenzofuran |
|
32 |
27 |
(0.0002) |
5 |
0.12 |
0.20 |
0.31 |
14% |
0.00001 |
1,2,3,6,7,8-hexachlorodibenzofuran |
|
32 |
28 |
(0.0001) |
9 |
0 |
0.0283 |
0.0861 |
26% |
0.000002 |
1,2,3,7,8,9-hexachlorodibenzofuran |
|
32 |
32 |
(0.0002) |
0 |
|
|
|
0% |
|
(0.00000001) |
|
|
|
|
|
|
|
|
|
|
2,3,4,6,7,8-hexachlorodibenzofuran |
|
32 |
27 |
(0.0002) |
10 |
0 |
0.0212 |
0.1776 |
29% |
0.000001 |
Hexachlorodibenzofurans (total) |
|
47 |
20 |
(0.0003) |
27 |
0.0059 |
0.3394 |
1.1381 |
54% |
0.00002 |
1,2,3,4,6,7,8-heptachlorodibenzo-p dioxin |
|
32 |
23 |
(0.0004) |
9 |
0.0051 |
0.0777 |
0.2982 |
26% |
0.000004 |
Heptachlorodibenzo-p-dioxins (total) |
|
47 |
28 |
(0.0004) |
19 |
0.005 |
0.281 |
1.047 |
38% |
0.00002 |
1,2,3,4,6,7,8-heptachlorodibenzofuran |
|
32 |
25 |
(0.0003) |
7 |
0.0051 |
0.0887 |
0.1822 |
20% |
0.000005 |
1,2,3,4,7,8,9-heptachlorodibenzofuran |
|
32 |
28 |
(0.0001) |
9 |
0 |
0.0576 |
0.2157 |
26% |
0.000003 |
Heptachlorodibenzofurans (total) |
|
44 |
17 |
(0.0003) |
27 |
0.007 |
0.204 |
1.138 |
57% |
0.00001 |
Octachlorodibenzo-p-dioxin |
|
47 |
27 |
(0.002) |
20 |
0.015 |
0.183 |
0.634 |
40% |
0.00001 |
Octachlorodibenzofuran |
|
50 |
42 |
(0.001) |
8 |
0.018 |
0.152 |
0.426 |
15% |
0.000008 |
Total dioxins & furans |
|
40 |
0 |
|
40 |
0.010 |
1.372 |
8.645 |
100% |
0.00009 |
International toxic equivalency ( 1989 |
|
36 |
36 |
|
39 |
0.001 |
0.037 |
0.206 |
100% |
0.000003 |
ITEQ calculated setting all BDL values to 0 |
|
35 |
0 |
|
35 |
0.0 |
0.010 |
0.131 |
100% |
0.000001 |
a Average annual reference air concentrations (RAC) and risk specific dose (RsD) values in μg/m3 are taken from 40 CFR 266, Appendices IV and V. RsD values are shown in parentheses. The RAC is 0.1 μg/m3 for SOPCs without a pollutant-specific RAC or RsD. Since the emitted concentration ranges are between 642,000 (MPF), 919,000 (LIC), and 1,350,000 (DFS) times greater than the annual average concentration represented by the RAC and RsD, to compare these inhalation pathway-based concentrations with measured concentrations and detection limits, multiply the RAC or RsD by 1,000,000 for particulates and metals. The multiplier for trace organic emissions is 1,000,000,000 to account for the difference in reported units. b Nondetected concentrations with detection limits above detected values for other sampling intervals have been excluded from the table to facilitate summary presentation of the data. To determine the number of these runs, subtract the number of detects and nondetects less than the lowest detected value from the total number of runs. |
Source: Compiled from data in sources listed below. JACADS Data Sources: Metco Environmental. 1992a. Source Emissions Survey of Johnston Atoll Chemical Agent Disposal System Liquid Incinerator Stack [LIC/GB]. Prepared for Southern Research Institute, August 1992. Addison, Texas: Metco Environmental. Metco Environmental. 1992b. Source Emissions Survey of Johnston Atoll Chemical Agent Disposal System Liquid Incinerator Stack [LIC/VX], February and March 1992. Prepared for Southern Research Institute, February 1992. Addison, Texas: Metco Environmental. Raytheon Engineers & Constructors, Inc. 1995. RCRA Trial Burn Report for Agent GB/Dunnage, in the Dunnage Incinerator at the Johnston Atoll Chemical Agent Disposal System [DUN/GB]. Prepared for Program Manager for Chemical Demilitarization, March 1995. Philadelphia, Pa.: Raytheon Engineers & Constructors, Inc. SRI. 1991. Results of the RCRA Trial Burn with GB Feed for the Liquid Incinerator at the Johnston Atoll Chemical Agent Disposal System [LIC/GB]. Prepared for Program Manager for Chemical Demilitarization, June 17, 1991. Birmingham, Ala.: Southern Research Institute. SRI (Southern Research Institute). 1992a. Results of the RCRA Trial Burn with VX Feed for the Liquid Incinerator at the Johnston Atoll Chemical Agent Disposal System, Volume IV (SRI-APC-92-384-7530.11.1-I) [LIC/VX]. Prepared for Program Manager for Chemical Demilitarization. Birmingham, Ala.: Southern Research Institute. SRI. 1992b. Results of the RCRA Trial Burn of the Metal Parts Furnace System with HD at the Johnston Atoll Chemical Agent Disposal System, Volume II (SRI-APC-92-834-7530.9.l-I) [MPF/HD]. Prepared for Program Manager for Chemical Demilitarization. Birmingham, Ala.: Southern Research Institute. SRI. 1992c. Results of the RCRA Demonstration Burn with HD Feed for the Liquid Incinerator at the Johnson Atoll Chemical Agent Disposal System, Volume IV, Appendix F (SRI-APC-92-7530.10.1-I) [LIC/HD]. Prepared for Program Manager for Chemical Demilitarization. Birmingham, Ala.: Southern Research Institute. United Engineers (United Engineers & Constructors, Inc.). 1992. RCRA Trial Burn Report for HD-Mustard Ton Containers-Metal Parts Furnace at the Johnston Atoll Chemical Agent Disposal System [MPF/HD]. Prepared for Program Manager for Chemical Demilitarization, December 16, 1992. Philadelphia, Pa.: United Engineers & Constructors, Inc. United Engineers. 1993. Results of the Demonstration Test Burn for Thermal Destruction of Agent HD in the Johnston Atoll Chemical Agent Disposal System Liquid Incinerator, [LIC/HD]. Prepared for Program Manager for Chemical Demilitarization, February 1993. Philadelphia, Pa.: United Engineers & Constructors, Inc. TOCDF Data Sources: Alliance Technologies Corporation. 1992. RCRA Compliance Test Results with Mixed Agent HD/Munitions for the Cryofracture Program on the Deactivation Furnace System, Chemical Agent Munitions Disposal System [DSF/HD]. Prepared for Program Manager for Chemical Demilitarization. Windsor, Conn.: TRC Environmental Corp. EG&G. 1995. Tooele Chemical Disposal Facility (TOCDF), Surrogate Trial Burn Report for Liquid Incinerator Number 1 [LIC/STB]. Prepared for Program Manager for Chemical Demilitarization, November 29, 1995. Tooele, Utah: EG&G Defense Materials, Inc. EG&G. 1997a. MPF GB ATB Report, Rev. 2 (partial report), [MPF/GB]. Prepared for Southern Research Institute, December 31, 1997a. Tooele, Utah: EG&G Defense Materials, Inc. |
EG&G. 1997b. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Liquid Incinerator System #2 [LIC/GB]. Prepared for Southern Research Institute, October 27, 1997. Tooele, Utah: EG&G Defense Materials, Inc. EG&G. 1997c. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Metal Parts Furnace, Appendices A-K [MPF/GB]. Prepared for Program Manager for Chemical Demilitarization, August 15, 1997. Tooele, Utah: EG&G Defense Materials, Inc. EG&G. 1997d. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Liquid Incinerator System #1, Appendices A-K, [LIC/GB]. Prepared for Program Manager for Chemical Demilitarization, July 7, 1997. Tooele, Utah: EG&G Defense Materials, Inc. EG&G. 1997e. Tooele Chemical Agent Disposal Facility (TOCDF), DFS TSCA Demonstration Test Burn Report for the Deactivation Furnace System [DFS/GB]. Prepared for Program Manager for Chemical Demilitarization, April 24, 1997. Tooele, Utah: EG&G Defense Materials, Inc. EG&G. 1997f. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent GB Trial Burn Report for the Deactivation Furnace System [DFS/GB], Appendices A-J. Prepared for Program Manager for Chemical Demilitarization, April 9, 1997. Tooele, Utah: EG&G Defense Materials, Inc. EG&G (EG&G Defense Materials, Inc.). 1998. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Deactivation Furnace System [DSF/ GB]. Prepared for Southern Research Institute, January 14, 1998. Tooele, Utah: EG&G Defense Materials, Inc. TRC (TRC Environmental Corporation). 1993a. Results of the Chromium Emissions Test Program on the Deactivation Furnace System Baseline Test Conditions, Chemical Agent Munitions Disposal System (CAMDS), Tooele, Utah [DFS/Propane]. Prepared for Program Manager for Chemical Demilitarization, May 1993. Aberdeen Proving Ground, Md.: U.S. Army Program Manager for Chemical Demilitarization. TRC. 1993. RCRA Compliance Test Results with Mixed Agent VX/Munitions for the Cryofracture Program on the Deactivation Furnace System, Chemical Agent Munitions Disposal System [DFS/VX]. Prepared for Program Manager for Chemical Demilitarization, October 1993. Aberdeen Proving Ground, Md.: U.S. Army Program Manager for Chemical Demilitarization. |