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Opportunities in Chemistry (1985) / Chapter Skim
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Pages 337-344

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From page 337...
... Index A Acentric materials, 59 Acid rain, 37, 192, 202-204 Adsorbed molecules, 22-24, 243245, 257 Aging process, 174 Agonists, 127, 130 Agriculture, 106-122, 323-324 Department of, see Federal agencies Air, clean, 24, 193-205, 325, 326 American Chemical Society members, fields of, 331 Analytical chemistry, 10, 195-199, 234-235, 252-258, 297, 320, 325, 326 instrumentation for, 219 separations, 252-253 Angiotensin-converting enzyme inhibitors, 124, 130 Antagonists, 127, 130 Antiarrhythmic therapy, 131 Antibacterials, 127-128 Antibiotic research, 127-129 Antibodies, 163 Anticancer agents, 135 Antidepressants, 132 Antifeedants, 113-114 Antifungals, 128 Antigens, 129 Antihypertensive compounds, 130 Anti-inflammatory agents, 137 Antijuvenile hormones, 112-113 Antimetabolites, 135 Antiviral agents, 128-129 Arhythmia, 131-132 Arthritis, 137 Artificial enzyme catalysis, 29-31, 295 Asymmetric catalysts, 78 Atherosclerosis, 130-131, 143 Atmospheric carbon dioxide, 41, 192, 204-205 Atomic energy, 44 Automobile industry, 212-213 B Baccalaureate chemistry education, 280, 285-287 Bacteria, 128 Balance of trade, 7-8, 290, 329 Batteries, 33, 58 Bimolecular reactions, 72 Bioactive molecules, 105, 120-121, 124, 143, 155-177 Biocatalysis, 150-152 Biochemistry, computational, 97 structure and function in, 170171 Bioengineering, 150 Bioinorganic chemistry, 80 Biological weapons, 234-236 Biomass energy source, 40-41 industrial chemicals from, 152 Biomedicine, 255-256 Biomimetic enzymes, 31 Biosynthesis, 155-163 Biotechnologies, 7, 144-152, 213214 Bitumin, 40 Block polymers, 52-53 C Cancer diagnosis and prevention of, 175-177 research, 133-136 Capillary chromatography, 273274 Carcinogenesis, 133-135 Cardiovascular disease, 129-132 Catalysis, 9, 11, 19, 21-22, 224, 295-296, 314, 320 artificial enzymes, 29-31, 295 biocatalysis, 150-152 electrocatalysis, 27-28, 296 heterogeneous, 19, 22-24, 35, 240-241 homogeneous, 24-27, 83, 157 metal, 23-24, 35, 242 organometallic, 24-27, 83, 157 photocatalysis, 27-28, 296 stereospecific, 26-27, 78 Catalysts, 22, 224 asymmetric, 78 chiral, 78 conversion, 24 environment and, 24 enzyme-like, 29-31 heterogeneous, 23, 35, 242, 295 homogeneous, 24, 83, 295 precious metal, 19, 24-26, 35, 76, 245 stereoselective, 26-27, 78 Catalytic cracking, 35 Central nervous system (CNS) , drugs affecting, 132-133 Ceramics, high technology, 81, 214 Chemical bonding at surfaces, 243-245 etching, 53-54, 218 feedstocks, 25, 211 fields of ACS members, 331 kinetics, 8, 63, 73-74, 232, 312, 320 of combustion, 37, 232, 312, 320 laser, HE, 68, 93 processes, 21-31 reactions, 21-103 dynamics of, 63-74, 294, 297298 electron transfer, 87 fast, 64-65 mechanisms, 37, 73, 83 new pathways of, 75-90 at surfaces, 72-74 theory of, 74-75, 87 reactivity, 11, 63, 294-295 synthesis, 9, 76-79, 155-163 artificial enzymes, 30-31 biological molecules, 106-118, 125-141 DNA, 161-162 inorganic, 81-84 337
From page 338...
... , 235-236 Cluster compounds, 26, 81-82 Co-adsorption on surfaces, 244-245 Coal, 34, 38-39, 311 Color photography, 216 Combustion of acetylene, 37 chemical kinetics of, 37, 232, 312, 320 of ethylene, 68-69 of natural gas, 37 products of, containment, 232233 turbulent systems, 233-234 Companies performing R and D, 330 Competitiveness, 7-8, 21, 209-221 Composites, 47, 59, 214-215 Computational biochemistry, 97 Computer-aided spectrometers, 96, 276-277 Computer graphics, 188 Computers, see Instrumentation, computers Condensed phase studies, 247 Conductors glasses, 59 novel electrical, 55-59 organic, 57 polymeric, 57 semiconductors, 55, 218 solid state ionic, 58 stacks, 55-56 superconductors, 57-58 Conformations of DNA and RNA, 168-170 Conformations of proteins, 163165 Contraceptives, 138-139 Contributors, 332-336 Conversion catalysts, 24 Coronary heart disease, 129 Corrosion, 215, 310 Critical materials, 222, 225 Critical phenomena, fluid, 250-251 "Cubane" structure, 26, 88 D DDT, 194 Decontamination methods, 236 Dedicated instrumentation, 305307 Defense frontiers, 237 Department of Agriculture (USDA) , see Federal agencies, USDA Department of Defense (DOD)
From page 339...
... , 102-103 Electron spin resonance (ESR) , 189-190 Electron transfer reactions, mechanisms, 87 Electronic phenomena in solids, 247-248 Electrophoresis, 121, 125 Employed doctorate recipients, 330 Employed scientists and engineers, 329 Enantiomers, 115 ENDOR (electron and nuclear magnetic double resonance)
From page 340...
... , 102-103 short wavelength, 92 tunable, 92 types, 93 maintenance and operation, expenses of, 304, 318 mass spectrometry, 183-185 applications, 121, 125, 254256, 258, 234-235 costs, 184 molecular beams, 98-99 applications, 68-71, 82 costs, 99 neutron diffraction, 121, 164, 188 nuclear magnetic resonance (NMR) , 178-182 applications, 43, 74, 83, 105, 121, 125, 160, 178, 258, 264 costs, 181 imaging, 180, 264 solid state, 179 two-dimensional, 180 obsolescence, 304 optical spectroscopy, 253-254 radioactivity, 259-260, 263 Raman, 278 coherent, 70, 92 surface-enhanced, 29, 245 scintillation counter, 278 sequencer, protein, 278 shared, 303-305, 318 surface sciences, 265-271 applications, 19, 241, 244, 257 costs, 268 synchrotrons, 99-102 applications, 101, 267 costs, 102 synthesizer, oligonucleotide, 171, 278 X-ray diffraction, 185-187 applications, 74, 121, 125, 144, 151, 154, 164, 167-168 costs, 187 Intellectual frontiers, 63-90, 155177, 240-263 analytical chemistry, 251-258, 297 biosynthesis, 155-163 catalysis, 22-30, 77-78, 240244, 295 chemical reactivity, 63-74 condensed phases, 247-250 critical phenomena, 250-251 DNA chemical synthesis of, 161-162 structure of, 168-172 electrocatalysis, 296 energy transfer and movement, 65-67 extreme conditions, 59-60, 76, 250-251, 298-299 fast reactions, 64-65 geochemistry, 251 genetic engineering, 168-170, 296-297 high pressure reactions, 97, 250251, 298-299 high speed reactions, 64-67, 230-236 high temperature reactions, 299-300 inorganic chemistry, 79-84 life processes, 155-177, 296 liquids, 248-250 low temperature reactions, 66, 69, 82, 300 301 macromolecules, structures of, 163-170 materials, 49-53, 54-60, 89-90, 295 molecular dynamics, 63-74, 249 multiphoton excitation, 69-71 natural product synthesis, 157163 nuclear chemistry, 259-264 organic chemistry, 75-79 organometallic compounds, 8284, 85-89 photochemistry, 87-88 plasma chemistry, 300 polymers, 48-54, 56-57, 90
From page 341...
... , 241, 267 341 Low-temperature chemistry, 300301 M Macrocycles, 56 Macromolecules, 125, 144, 163-175 Mainframe computers, 97 Maintenance of research instrumentation, cost of, 304, 318 Malnutrition, 106 Manpower and education, 279-287 Manufacturers' shipments, 329 Mass spectrometry, 183-186, 254255 tandem (MS/MS) , 234-235, 256257 Materials, 6, 9, 48-60 acentric, 59 critical, 222-223 defined, 48 earth, 251 extraterrestrial, 251 for extreme conditions, 59-60 high-temperature, 60 optical fibers, 54-55 polymers, 47, 48-54 solid-state, 89-90, 223-224 strategic, 222-223 structural, polymers as, 50-51 Matrix isolation method, 72, 300 Medicine, 125-141 biotechnology applied to, 148149 nuclear chemistry in, 263-264 Messenger RNA (mRNA)
From page 342...
... Chemical behavior under extreme conditions, 12, 298301 high pressure chemistry, 77, 250-251, 298-299 high temperature chemistry, 59-60, 299-300 low temperature chemistry, 66, 69, 72, 82, 300-301 plasmas, 59-60, 300 Portfolio concept of research funding, 10, 293 Processes, new, 21-31, 39, 118-119 Products, new, 48-60, 89-90, 144152 Protein confirmational studies, 163-166 Protooncogenes, 175-176 R Radioactive isotopes, 260-264 Radioactive waste management, 44, 208 Radiochemistry, 229-230 Rain, acid, 37, 192, 202-204 Raman effect coherent, 70, 92 surface-enhanced, 28, 245 Reactors fusion, 44-45 nuclear, 44, 228 Receptor-substrate interactions, 126-127, 296 Recombinant DNA technologies, 146-148, 160-161 Recommendations, 11-18 Department of Agriculture #9, 17, 323-324 competitive grant program, 324 Department of Defense #8, 15, 318-323 basic (6.1) research support, 319 instrumentation and facilities, 323 priority areas, 320 university research, 321 Department of Energy #6, 14, 310-314 chemistry budget should grow, 15, 310 energy technology research initiative needed, 15, 311312 National Laboratory missions reshaped toward chemistry, 15, 312, 314 university research program should grow, 15, 312 Environmental Protection Agency #11, 17, 325-326 federal research investment should increase #4, 12, 290 industrial-academic linkages needed #2, 12, 289 industrial support for academic research encouraged #3, 12 National Aeronautics and Space Administration #10, 16, 324-325 priority areas, 324 National Institutes of Health #7, 14, 315-318 cross-disciplinary grants, 316 grant size increased, 316 grant stabilization encouraged, 318 shared instrumentation program, 313
From page 343...
... sources, 92 Solar cells, 59 Solar energy, 41-43 Solar neutrino experiments, 263 Solid/liquid interface, 28-29 Solid state, 89-90, 223-224 ionic conductors, 58 NMR, 179-180 Solids, 89-90 electronic phenomena in, 247248 self-organized, 52-53 Space environment, library books and, 239 Space exploration, 261-262 Spectrometry, mass (MS) , see Instrumentation, MS Spectroscopy computer-aided, 276-277 nuclear, 260 optical, 253-254 technologies, 246-247 X-ray, 76 Speeds, computing, 94, 96 Starvation, 106 State-to-state chemistry, 67-69 Stereochemistry, 77-79 Stereoisomers, 168 Stereoselective catalysts, 26-27 Stereoselectivity, 84 Steroid glycosides, 131 Steroid hormones, 138 Strategic materials, 222 Stratospheric ozone, 199-202 Structural materials, polymers as, 50-51 Summary, executive, 6-18 Supercomputers, 97 Superconductors, 57-58 Superminicomputers, 96-97 Surface analysis, 257, 269-271 chemistry, 223, 240-247 composition, 242-243 dynamic phenomena, 245 electrical properties, 246 science, 23 science instrumentation, 265271 Surface-enhanced Raman effect, 29 Surfaces chemical bonding at, 243-244 co-adsorption on, 244-245 electrode, 258 reaction chemistry of, 72-74, 81 solid, 240-247 Surveillance, rocket, 226-227 Switches, optical, 54-55 Synchrotron radiation, 99-102 applications of, in chemistry, 101 costs, 101-102 Tunable lasers, 92 Turbulent combustion systems, 233-234 Two-dimensional chromatography, 253 Two-dimensional NMR, 180 U Ulcers, 136 Ultrafine filamentary composites, 81 Ultraviolet photoelectron spectroscopy, 267 Urbanization, 193 USDA, see Federal agencies, USDA V Vaccines, 148-149 viral, 129 Van der Waals molecules, 82 Vasodilators, 131 Vectorial chemistry, 296 Vignettes Beauty is only skin deep, 19 Investigating smog soup, 192 Jack and soybean stalk, 154 Libraries into space, 239 Lithium powered heart, 33 Pac-man for cholesterol, 143 Rx-snake bite, 124 Stone age, iron age, polymer age, 47 Time to wag a tail, 62 Whipping a wicked weed, 105 Viral vaccines, 129 Viruses, 128-129 oncogenic, 175 Vitamins, 76, 139-140 W Waste disposal, safe, 206-208 Waste management, radioactive, 44, 208 Water, clean, 24, 206-208 Wiggler field, 102
From page 344...
... 344 INDEX X X-ray absorption fine structure, extended (EXAFS) , 101, 267 crystallography, 126, 144, 150, 166-167 diffraction, 154, 166, 179, 186188, 267 photoelectron spectroscopy (ESCA)


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